Exploitation of Mechanostress-Induced Molecular Aggregation and Its Application to Functional Molecular Devices

探索了以机械应力为外界刺激，对衣夹形钯铂配合物的流动性和分子重排进行清洁、远程控制的方法，以期创造出新型功能材料。环状双核钯配合物的分子组装可以通过反应条件如超声时间、溶剂和其结构异构体的加入来控制。此外，相应的铂配合物被发现显示超声诱导的发射增强现象。

Clean and remote methods for controlling fluidity and molecular rearrangement of clothes-pin shaped palladium and platinum complexes by mechanostress as an external stimuli was explored in order to create a new functional materials. Molecular assembly of cyclic dinuclear palladium complex can be controlled by reaction conditions such as sonication time, solvent, and addition of its structural isomer. Furthermore, the corresponding platinum complexes were found to show sonication-induced emission enhancement phenomenon.