Solid-State Polymerization and Structure Control Based on Quinoid Compounds

制备了取代醌类化合物（取代醌二甲甲烷、取代醌甲醚、取代醌甲亚胺）晶体及其共晶，并在分析晶体单晶结构和固相聚合产物的基础上，讨论了晶体中分子间相互作用与固态聚合反应活性的关系。此外，还制备了新的取代醌类化合物，研究了它们的固溶聚合和溶液聚合，并讨论了聚合物一级结构的控制。

Substituted quinoid compounds (substituted quinodimethanes, substituted quinone methides, substituted quinone methide imines) crystals and theircocrystals were prepared, and the relationship of the solid-state polymerization reactivity with the intermolecular interaction between molecules in the crystals was discussed on the basis of their single-crystal structure analyses and their products obtained by solid-state polymerizations. And also, novel substituted quinone methides were prepared, and their solid-state and solution polymerizations were investigated and control of the primary structure of obtained polymers was discussed.