Concerto Redox Properties for Inorganic-Organic Hybrid Nanoclusters

利用两性离子配体和多种金属离子合成了新型无机-有机杂化纳米团簇。对所合成的簇合物进行了结构表征、电化学性质表征和光谱表征。在此基础上研究了多电子氧化还原体系中配体与金属的相互作用的电子结构特征。并利用计算方法对它们的电子态和结构进行了分析。开发了具有更复杂多电子氧化还原体系的新型两性离子配体。从这些结果尝试评价它们作为纳米材料的功能。对部分成果进行了论文投稿，并将结果公之于众。

New inorganic-organic hybrid Nanoclusters were synthesized by using Zwitter ionic ligands and various metal ions. The synthesized clusters were clarified about their structures in the solid and in solution, the electrochemical properties, and the spectroscopy characters. The interactions between ligands and metals for multi-electronic redox system of electronic and structural characters were examined based on the obtained results. The electronic state and the analyses of their structures were carried out by also using the computational calculations. The new Zwitter ionic ligands that showed more complex multi electron redox system were developed. The evaluation of their functionality as the Nano-material was tried from these results. Thesis submission was done for a part of the result of obtaining, and the result was made public.