Development of atom-economical and enantioselective catalytic radical reactions (B02)

在B2中，我们研究了解决可持续性和立体选择性问题的催化自由基反应。实例是自由基芳基化、环氧化物氢化硅烷化和区域发散环氧化物开口。催化剂设计基于跨学科的策略，依赖于理论和EPR项目的密切合作。我们的研究结果将表明，在单一的电子步骤，涉及“经典”的有机金属化学的自由基化学的催化的概念提供了一个可持续的，原子经济的和对映选择性的自由基反应的发展的一般设计原则。

In B2 we investigate catalytic radical reactions that address the issues of sustainability and stereose-lectivity. Examples are radical arylations, epoxide hydrosilylations, and regiodivergent epoxide openings. Catalyst design is based on an interdisciplinary strategy that relies on close cooperation with theoretical and EPR projects. Our results will demonstrate that the concept of catalysis in single elec-tron steps that relates 'classical' organometallic chemistry to radical chemistry provides a general design principle for the development of sustainable, atom-economical and enantioselective radical reactions.