Microstructure, mechanical and tribological properties of TiMoN/Si3N4 nano-multilayer films deposited by magnetron sputtering

Microstructure, mechanical and tribological properties of TiMoN/Si3N4 nano-multilayer films deposited by magnetron sputtering
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磁控溅射TiMoN/Si3N4纳米多层薄膜的微观结构、力学和摩擦学性能

DOI:
10.1016/j.apsusc.2014.11.125
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发表时间:
2015-01
影响因子:
6.7
通讯作者:
Jiang Bailing
Jiang Bailing
中科院分区:
材料科学1区
文献类型:
--
作者:
Wang Tao;Zhang Guojun;Jiang Bailing

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采用磁控溅射法,通过改变Si靶电流,制备了不同Si 3 N4层厚度的TiMoN/Si 3 N4纳米多层膜。TiMoN/Si 3 N4纳米多层膜的结构和性能与Si 3 N4层的结构密切相关。当Si_3N_4层厚度小于0.8nm时,Si_3N_4层仍保持晶化状态,TiMoN/SiNx薄膜的硬度和摩擦系数均比MoNx/SiNx薄膜高得多。随着Si_3N_4含量的进一步增加,Si_3N_4层向非晶态转变,TiMoN/Si_3N_4薄膜的硬度从29.9 GPa逐渐降低到20.1 GPa,COF从0.55增加到0.72。结果表明,与TiAlSiN/Si_3N_4纳米多层膜相比,氮化钼的加入使薄膜的摩擦学性能得到了明显的改善。
TiMoN/Si3N4nano-multilayer films with different Si3N4layer thickness were synthesized using magnetron sputtering by changing the Si target current. The TiMoN/Si3N4nano-multilayer films exhibited strong microstructure and properties dependence on the structures of Si3N4layer. When Si3N4layer thickness (lSi3N4) was smaller than 0.8 nm, Si3N4layers maintained crystallization state, the as-deposited TiMoN/SiNxfilms exhibited much higher hardness and comparable coefficient of friction (COF) than that of MoNx/SiNxfilms. With the further increase oflSi3N4, Si3N4layer transformed to amorphous state, the hardness of TiMoN/Si3N4films decreased gradually from 29.9 to 20.1 GPa and COF increased from 0.55 to 0.72. It totally shows better tribological properties than TiAlSiN/Si3N4nano-multilayer films as a result of incorporating molybdenum nitride.
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