One coordinate carbon and boron: Universal progenitor ligands

一配位碳和硼：通用祖配体

• 批准号: DP1093516
• 负责人: Prof Anthony Hill
• 金额: $ 33.39万
• 依托单位: The Australian National University
• 依托单位国家: 澳大利亚
• 项目类别: Discovery Projects
• 财政年份: 2010
• 资助国家: 澳大利亚
• 起止时间: 2010-01-01 至 2013-12-31
• 项目状态: 已结题
• 来源: https://dataportal.arc.gov.au/RGS/Web/Grants/DP1093516
• 关键词: coordinate; carbon; boron; Universal; progenitor

Compounds with bonds between metals and carbon (organometallic chemistry) underpin innumerable important industrial processes from fine chemicals to bulk agrochemical and polymer synthesis. Yet the simplest example, a single atom of carbon bound to a metal has only recently been discovered and is poorly understood. Australia's fledgling boron fine chemicals industry similarly benefits from metal-based processes. However, compounds with a single boron atom bound to a metal remain unknown. This proposal addresses metal-carbon and metal-boron chemistry from the most basic perspective, that of a single atom of boron or carbon, including the development of novel synthetic approaches and skills for the characterisation of such curious species.

金属和碳之间的化合物（有机金属化学）支撑着从精细化学品到大宗农用化学品和聚合物合成的无数重要工业过程。然而，最简单的例子，一个碳原子与金属结合，直到最近才被发现，而且人们对此知之甚少。澳大利亚刚刚起步的硼精细化学品工业同样受益于金属工艺。然而，具有单个硼原子与金属结合的化合物仍然未知。该提案从最基本的角度，即硼或碳的单个原子的角度，讨论了金属-碳和金属-硼化学，包括开发新的合成方法和技术来表征这种奇怪的物种。