Fluorination of Unsaturated Hydrocarbons with Xenon Difluoride

在这个有机动力学项目中， 化学部，教授戴尔F。Shellhamer在 Point Loma Nazarene College化学系 二氟化氙与不饱和烃的反应 在质子溶剂中，为了更好地理解 反应途径。 该项目将提供研究 对本科生的培训。 二氟化氙与不饱和烃的反应 （烯烃、不饱和酮、1，3-二烯和芳烃） 将研究质子溶剂（醇和水）。 一 对这些反应的动力学和产物的研究将 更好地理解反应机制。 无环1，3-二烯离子交换的早期研究 与二氟化氙在非质子和质子溶剂中的反应， 延伸到包括环状二烯。 立体异构体来自 用二氟化氙取代环二烯， 与先前报告的溴化数据相比， 氯化相同的环状二烯。

In this project in the Organic Dynamics Program of the Chemistry Division, Professor Dale F. Shellhamer in the Chemistry Department of Point Loma Nazarene College will study the reactions of xenon difluoride with unsaturated hydrocarbons in protic solvents in order to obtain a better understanding of the reaction pathway. This project will provide research training for undergraduate students. The reactions of xenon difluoride with unsaturated hydrocarbons (alkenes, unsaturated ketones, 1,3-dienes, and aromatics) in protic solvents (alcohols and water) will be investigated. A study of the kinetics and products of these reactions will allow a better understanding of the reaction mechanisms. Earlier studies on the ionic fluorination of acyclic 1,3-dienes with xenon difluoride in aprotic and protic solvents will be extended to include cyclic dienes. The stereoisomers from fluorination of cyclic dienes with xenon difluoride will be compared to previously reported data for bromination and chlorination of the same cyclic dienes.