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A Study on the Generation of Interhalogen Fluorides

A Study on the Generation of Interhalogen Fluorides
卤间氟化物生成的研究
批准号:
9321094
负责人:
Dale Shellhamer
金额:
$7.23万
依托单位:
依托单位国家:
美国
项目类别:
Continuing Grant
财政年份:
1994
资助国家:
美国
项目状态:
已结题
起止时间:
1994-06-01 至 1997-11-30

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中文摘要
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英文摘要
9321094 Shellhamer This grant from the Organic Dynamics program supports the work of Professor Dale Shellhamer at Point Loma Nazarene College who will involve undergraduate students in the study of interhalogens XF (X= I,Br,Cl) synthesized from a combination of various electrophilic reagents. The resulting interhalogens will be added to a variety of unsaturated hydrocarbons with the goal of elucidating the versatility and utility for XF in synthesis. Evidence for the elusive cationic form of Xe-O will be sought. The synthesis of reagents containing N-F bonds as mild fluorination reagents will be studied. This research will enhance the understanding of species that are selective in fluorination reactions. %%% In this project Professor Dale Shellhamer will explore the unique behavior of fluorine containing compounds so that the very high reactivity of fluorine can be moderated. The results from these studies will develop utilitarian uses of specially designed fluorine reagents so that fluorine can be introduced into organic compounds under controlled conditions. ***
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RUI: Electrophilic Reactions of Fluorosubstituted Alkenes with Chlorosulfonyl Isocyanate and some other Electrophiles
  • 批准号:
    0948255
  • 项目类别:
    Standard Grant
  • 资助金额:
    $13.43万
  • 财政年份:
    2010
  • 负责人:
    Dale Shellhamer
  • 依托单位:
RUI: Electrophilic Reactions of Fluorosubstituted Alkenes- Predicting Regiochemical Product Distributions
  • 批准号:
    0640547
  • 项目类别:
    Standard Grant
  • 资助金额:
    $12.5万
  • 财政年份:
    2007
  • 负责人:
    Dale Shellhamer
  • 依托单位:
RUI: Electrophilic Reactions of Triflic Acid and Chlorosulfonyl Isocyanate with Fluorosubstituted Terminal Alkenes
  • 批准号:
    0345551
  • 项目类别:
    Standard Grant
  • 资助金额:
    $10.8万
  • 财政年份:
    2004
  • 负责人:
    Dale Shellhamer
  • 依托单位:
RUI: Electrophilic vs Free Radical Reactions of Halogen Systems with Terminal Perfluoroalkenes and Their Derivatives
  • 批准号:
    0091636
  • 项目类别:
    Standard Grant
  • 资助金额:
    $10.0万
  • 财政年份:
    2001
  • 负责人:
    Dale Shellhamer
  • 依托单位:
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