A Study on the Generation of Interhalogen Fluorides

卤间氟化物生成的研究

• 批准号: 9321094
• 负责人: Dale Shellhamer
• 金额: $ 7.23万
• 依托单位: Point Loma Nazarene College
• 依托单位国家: 美国
• 项目类别: Continuing Grant
• 财政年份: 1994
• 资助国家: 美国
• 起止时间: 1994-06-01 至 1997-11-30
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=9321094&HistoricalAwards=false
• 关键词: Study; Generation; Interhalogen; Fluorides

9321094 Shellhamer This grant from the Organic Dynamics program supports the work of Professor Dale Shellhamer at Point Loma Nazarene College who will involve undergraduate students in the study of interhalogens XF (X= I,Br,Cl) synthesized from a combination of various electrophilic reagents. The resulting interhalogens will be added to a variety of unsaturated hydrocarbons with the goal of elucidating the versatility and utility for XF in synthesis. Evidence for the elusive cationic form of Xe-O will be sought. The synthesis of reagents containing N-F bonds as mild fluorination reagents will be studied. This research will enhance the understanding of species that are selective in fluorination reactions. %%% In this project Professor Dale Shellhamer will explore the unique behavior of fluorine containing compounds so that the very high reactivity of fluorine can be moderated. The results from these studies will develop utilitarian uses of specially designed fluorine reagents so that fluorine can be introduced into organic compounds under controlled conditions. ***

9321094 谢尔哈默 有机动力学计划的这笔赠款支持 Dale Shellhamer教授在Point Loma Nazarene的工作 将本科生纳入研究的学院 的卤间化合物XF（X= I，Br，Cl）， 各种亲电试剂的组合。所得 卤素间化合物将被添加到各种不饱和的 碳氢化合物的目的是阐明多功能性 以及XF在合成中的用途。证据表明， 将寻求Xe-O的阳离子形式。的合成 含N-F键的试剂，作为温和的手性试剂 将被研究。 这项研究将提高 对选择性繁殖的物种的理解 反应. 在这个项目中，Dale Shellhamer教授将探索 含氟化合物的独特行为， 可以缓和氟的非常高的反应性。的 这些研究的结果将开发出 特别设计的氟试剂， 在控制下引入有机化合物中 条件 ***