A Mechanistic Study on the Generation of Interhalogen Fluorides and Electrophilic Additions to Perfluoroalkenes

卤间氟化物的生成及全氟烯烃的亲电加成机理研究

• 批准号: 9616442
• 负责人: Dale Shellhamer
• 金额: $ 8.7万
• 依托单位: Point Loma Nazarene College
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 1997
• 资助国家: 美国
• 起止时间: 1997-05-15 至 2000-04-30
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=9616442&HistoricalAwards=false
• 关键词: Mechanistic; Study; Generation; Interhalogen; Fluorides

One focus of this research is a mechanistic study to determine if a complex forms that delivers interhalogens to alkenes when xenon difluoride, amine.HF reagents of boron trifluoride serve as the source of fluorine. In a second part of the research, the ionic and/or ion-radical addition reactions of perfluoroalkenes will be probed. In both instances, undergraduates will form a major part of the research team. With this renewal Research in Undergraduate Institutions (RUI) award, the Organic Dynamics Program supports the research of Dr. Dale F. Shellhamer of the Department of Chemistry at Point Loma Nazarene College. Professor Shellhamer will focus his work on the study of the mechanism of organic reactions. Studying the generation of interhalogen fluorides and the ionic reactions of perfluoroalkenes provides an excellent venue for the training of undergraduate chemists.

这项研究的一个重点是一个机制的研究，以确定是否 当氙离子进入烯烃时， 三氟化硼的HF试剂用作三氟化硼的来源。 氟。 在研究的第二部分中，离子和/或离子自由基 将探测全氟烯烃的加成反应。 无论是 例如，本科生将成为研究团队的主要组成部分。 随着本科院校研究（RUI）奖的更新， 有机动力学项目支持Dale F.谢尔哈默 在Point Loma Nazarene学院的化学系工作。 教授 Shellhamer将把工作重点放在有机物作用机制的研究上 反应. 研究卤间氟化物的生成及其对环境的影响， 全氟烯烃的离子反应提供了一个极好的场所， 培养本科生化学家。