Synthetic Organosulfur Chemistry

有机硫合成化学

• 批准号: 9001173
• 负责人: Eric Block
• 金额: $ 32.5万
• 依托单位: SUNY at Albany
• 依托单位国家: 美国
• 项目类别: Continuing Grant
• 财政年份: 1990
• 资助国家: 美国
• 起止时间: 1990-06-01 至 1993-05-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=9001173&HistoricalAwards=false
• 关键词: Synthetic; Organosulfur; Chemistry

The Synthetic Organic Program is funding the research of Dr. Eric Block of the Department of Chemistry at the State University of New York (SUNY) at Albany. Dr. Block will continue his studies on the chemistry of the organic compounds of sulfur. Major areas of concern include the development of useful new sulfur-containing reagents for organic synthesis, the investigation of the structure, synthesis and reactions of unusual organosulfur compounds from onion and the study of important but little studied classes of organosulfur compounds. A novel class of reagents that permit the controlled growth of carbon-containing rings through "iterative Diels-Alder reactions" will be studied. Syntheses will be attempted that will afford polyacenes, compounds that are linear molecules containing side-by-side fused benzene rings, which, in the polymer (C4H2)n extreme, have been predicted to be electrical conductors. Related reagents will be used to develop a new synthesis of fused cyclopentadienes and a novel, catalytic process for the generation and trapping of singlet disulfur.

合成有机计划正在资助博士的研究。 加州大学化学系的Eric Block 位于奥尔巴尼的纽约大学。 布洛克医生会 继续研究有机化合物的化学 硫磺。 主要关注的领域包括： 用于有机合成的有用的新型含硫试剂， 研究了三聚氰胺的结构、合成和反应， 洋葱中常见的有机硫化合物及其生物活性的研究 重要但研究较少的有机硫化合物类别。 一类新的试剂，允许控制生长的 含碳环的“迭代Diels-Alder” 将研究“反应”。 将尝试合成， 将提供聚并苯，一种线性分子的化合物 含有并排稠合的苯环，在 聚合物（C4 H2）n极端，已被预测为电 导线. 相关试剂将用于开发新的 稠合环戊二烯的合成和一种新的催化剂 产生和捕获单线态二硫的方法。