Synthetic Organosulfur Chemistry

本研究的重点是有机化合物的化学， 硫和硒。 主要工作领域有六个方面，包括： 1)二硫英化学，特别是二硫英的合成和反应的研究 1，2-二噻辛的化学; 2）1，2-二噻辛的合成和研究， 1，4-二硫杂环辛，1，2-二硫杂环辛的高级环同系物， 单重态S2的来源; 3）葱属植物化学研究; 4）调查 香菇食用香料的化学研究; 5）开发新的 用于有机合成的试剂，和; 6）表征高度 反应性小的有机硫化合物使用微波光谱。 有了这个更新奖，合成有机计划正在支持 奥尔巴尼纽约州立大学化学系的埃里克·布洛克博士的研究。 布洛克教授将把工作重点放在有机化合物的化学上 硫和硒。 这项基础广泛的研究中的项目 程序范围从大蒜和洋葱的化学研究， 有机合成新试剂的开发。

The focus of this research is on the chemistry of organic compounds of sulfur and selenium. Major areas of effort are six-fold and include: 1) Dithiin chemistry, especially the synthesis and study of the reaction chemistry of 1,2-dithiins; 2) Synthesis and study of 1,2-dithiocins, 1,4-dithiocins, higher ring homologs of 1,2-dithiins and likely thermal sources of singlet S2; 3) Research on Allium chemistry; 4) Investigation of the chemistry of shiitake mushroom flavorants; 5) Development of new reagents for organic synthesis, and; 6) Characterization of highly reactive small organosulfur compounds using microwave spectroscopy. With this renewal award, the Synthetic Organic Program is supporting the research of Dr. Eric Block of the Chemistry Department at SUNY, Albany. Professor Block will focus his work on the chemistry of organic compounds of sulfur and selenium. The projects in this broadly based research program range from the study of the chemistry of garlic and onion to the development of new reagents for organic synthesis.