Synthetic Organosulfur Chemistry

有机硫合成化学

• 批准号: 9628774
• 负责人: Eric Block
• 金额: $ 34.5万
• 依托单位: SUNY at Albany
• 依托单位国家: 美国
• 项目类别: Continuing Grant
• 财政年份: 1996
• 资助国家: 美国
• 起止时间: 1996-07-01 至 1999-05-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=9628774&HistoricalAwards=false
• 关键词: Synthetic; Organosulfur; Chemistry

The focus of this research is on the chemistry of organic compounds of sulfur and selenium. Major areas of effort are six-fold and include: 1) Dithiin chemistry, especially the synthesis and study of the reaction chemistry of 1,2-dithiins; 2) Synthesis and study of 1,2-dithiocins, 1,4-dithiocins, higher ring homologs of 1,2-dithiins and likely thermal sources of singlet S2; 3) Research on Allium chemistry; 4) Investigation of the chemistry of shiitake mushroom flavorants; 5) Development of new reagents for organic synthesis, and; 6) Characterization of highly reactive small organosulfur compounds using microwave spectroscopy. With this renewal award, the Synthetic Organic Program is supporting the research of Dr. Eric Block of the Chemistry Department at SUNY, Albany. Professor Block will focus his work on the chemistry of organic compounds of sulfur and selenium. The projects in this broadly based research program range from the study of the chemistry of garlic and onion to the development of new reagents for organic synthesis.

这项研究的重点是硫和硒有机化合物的化学。 主要工作领域有六方面，包括：1）二硫化合物化学，特别是1,2-二硫化合物的合成和反应化学研究； 2) 1,2-二硫辛、1,4-二硫辛、1,2-二硫辛高环同系物的合成与研究以及单线态S2可能的热源； 3）葱属化学研究； 4）香菇食用香料的化学研究； 5) 有机合成新试剂的开发； 6) 使用微波光谱法表征高活性小有机硫化合物。 凭借这一续签奖项，合成有机项目正在支持纽约州立大学奥尔巴尼分校化学系埃里克·布洛克博士的研究。 布洛克教授的工作重点是硫和硒有机化合物的化学。 这个基础广泛的研究计划的项目范围从大蒜和洋葱的化学研究到有机合成新试剂的开发。