RUI: Phenyl Selenide Transfer Radical Reactions

RUI：苯基硒化物转移自由基反应

• 批准号: 9406706
• 负责人: Jeffrey Byers
• 金额: $ 12.25万
• 依托单位: Middlebury College
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 1994
• 资助国家: 美国
• 起止时间: 1994-07-15 至 1998-06-30
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=9406706&HistoricalAwards=false
• 关键词: RUI; Phenyl; Selenide; Transfer; Radical

9406706 Byers The focus of this research is the development of new carbon-carbon bond forming reactions using free-radicals generated from organoselenides. Due to the specific reactivity of the phenyl selenide group, this methodology will be utilized to synthesize several important classes of organic compounds such as the amino acids, the butanolides, and the tetronic acids. With this Renewal RUI award, the Synthetic Organic Program is supporting the research of Dr. Jeffrey H. Byers of the Department of Chemistry of Middlebury College. Professor Byers will focus his research on development of new carbon-carbon bond forming reactions, one of the most important classes of reactions in organic chemistry, using free-radicals generated from organoselenides.

9406706 Byers 这项研究的重点是利用有机硒化物产生的自由基开发新的碳-碳键形成反应。由于苯基硒化物基团的特定反应性，该方法将用于合成几类重要的有机化合物，例如氨基酸、丁内酯和特窗酸。 凭借这一 RUI 续约奖，合成有机项目正在支持米德尔伯里学院化学系的 Jeffrey H. Byers 博士的研究。拜尔斯教授的研究重点是开发新的碳-碳键形成反应，这是有机化学中最重要的反应类别之一，利用有机硒化物产生的自由基。