U.S.-Australia Cooperative Research: Matrix Isolation Spectroscopy of Alkyl and Cycloalkylcarbenes

美国-澳大利亚合作研究：烷基和环烷基卡宾的基质分离光谱

• 批准号: 9513227
• 负责人: Matthew Platz
• 金额: $ 1.69万
• 依托单位: Ohio State University Research Foundation -DO NOT USE
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 1996
• 资助国家: 美国
• 起止时间: 1996-05-01 至 1998-04-30
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=9513227&HistoricalAwards=false
• 关键词: U.S.; Australia; Cooperative; Research; Matrix

9513227 Platz This award supports the travel costs for Dr. Matthew Platz from the Department of Chemistry at the Ohio State University to enable him to make a three month stay conducting collaborative research with Prof. Curt Wentrup of the Queensland University Department of Chemistry. Dr. Platz will use this period to study dialkyl and cycloalkylcarbenes by the technique of matrix isolation spectroscopy. The investigators will attempt to isolate simple carbenes in cryogenic matrices and to characterize them through UV-Vis and IR spectroscopy. This work will determine the ground state multiplicity of simple carbenes. This projects draws together the complementary expertise of Prof. Platz in the area of carbene reactivity, using laser flash photolysis, fluorescence and EPR spectroscopy, with that of Prof. Wentrup in matrix isolation.

小行星9513227 该奖项支持俄亥俄州州立大学化学系的Matthew Platz博士的差旅费，使他能够与昆士兰州大学化学系的Curt Wentrup教授进行为期三个月的合作研究。 普拉茨博士将利用这段时间研究二烷基和环烷基卡宾的基质隔离光谱技术。 研究人员将尝试在低温基质中分离出简单的卡宾，并通过紫外可见光谱和红外光谱对其进行表征。这项工作将确定简单卡宾的基态多重性。 该项目汇集了Platz教授在卡宾反应性领域的互补专业知识，使用激光闪光光解，荧光和EPR光谱，以及Wentrup教授在基质分离方面的专业知识。