New Polyvalent Iodine Reagents

新型多价碘试剂

• 批准号: 9802823
• 负责人: Viktor Zhdankin
• 金额: $ 18万
• 依托单位: University of Minnesota-Twin Cities
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 1998
• 资助国家: 美国
• 起止时间: 1998-05-01 至 2001-04-30
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=9802823&HistoricalAwards=false
• 关键词: New; Polyvalent; Iodine; Reagents

The focus of this research, carried out in an undergraduate setting, is the preparation and utilization of alkyliodonium derivatives, perfluoroalkyl iodonium salts, benziodoxoles, cyclic derivatives of pentavalent iodine, and new compounds of lead(IV) and Xenon(II). The long-term goals of the research include: (i) the extension and improvement of basic knowledge on the structure and reactivity of polyvalent iodine compounds, (ii) the creation of new reagents and of procedures suitable for organic synthesis, and (iii) the search for reaction products with useful applications. With this renewal Research in Undergraduate Institutions award, the Organic and Macromolecular Chemistry Program is supporting the research efforts of Dr. Viktor V. Zhdankin of the Department of Chemistry at the University of Minnesota, Duluth. With his undergraduate colleagues, Dr. Zhdankin will focus his work on the synthesis of new structural types of trivalent and pentavalent iodine with the goal of developing new reagents for organic synthesis.

这项研究的重点是在本科环境中进行的，是烷基碘鎓衍生物、全氟烷基碘盐、苯并碘多唑、五价碘的环衍生物以及铅（IV）和氙（II）的新化合物的制备和利用。这项研究的长期目标包括：(i)扩展和改进关于多价碘化合物的结构和反应性的基本知识；（ii）创造适合有机合成的新试剂和程序；（iii）寻找具有有用应用的反应产物。有机和大分子化学项目通过更新本科院校研究奖，支持了明尼苏达大学德卢斯分校化学系Viktor V. Zhdankin博士的研究工作。Zhdankin博士将与他的本科同事一起专注于合成新结构类型的三价和五价碘，目标是开发用于有机合成的新试剂。