Organic Chemistry of Hypervalent Compounds

在有机和大分子化学项目的支持下，明尼苏达大学德卢斯分校化学系的Viktor V. Zhdankin教授正在探索碘和铋的高价化合物的化学性质。他的研究包括新型高价碘和含铋杂环化合物的制备和结构表征，七价碘有机衍生物的合成方法的评价，以及基于高价碘配合物、碘杂环、氨基酸衍生的高价碘二羧酸盐和磷烷衍生的碘烷的新合成方法的发展。有了这个本科院校研究奖，有机和大分子化学项目为德卢斯明尼苏达大学化学系Viktor V. Zhdankin教授的研究工作提供了新的支持。通过对含碘或含铋化合物的新结构类型的研究，Zhdankin教授将增强我们对这些不寻常化合物的结构和反应性的理解，开发有机合成的新试剂和新方法，并寻找具有不寻常和有用性质的新化合物。这些研究将主要由明尼苏达大学德卢斯分校的本科生进行。

With the support of the Organic and Macromolecular Chemistry Program, Professor Viktor V. Zhdankin, of the Department of Chemistry at the University of Minnesota, Duluth, is exploring the chemistry of hypervalent compounds of iodine and bismuth. His studies include the preparation and structural characterization of new classes of hypervalent iodine- and bismuth-containing heterocycles, the evaluation of synthetic approaches to organic derivatives of heptavalent iodine, and the development of new synthetic methodologies based on hypervalent iodine complexes, iodine heterocycles, amino acid-derived hypervalent iodine dicarboxylates, and phosphorane-derived iodanes.With this Research in Undergraduate Institutions award, the Organic and Macromolecular Chemistry Program is providing renewed support for the research efforts of Professor Viktor V. Zhdankin, of the Department of Chemistry at the University of Minnesota, Duluth. Through the study of new structural types of compounds containing iodine or bismuth, Professor Zhdankin will enhance our understanding of the structure and reactivity of these unusual compounds, develop new reagents and procedures for organic synthesis, and search for new compounds with unusual and useful properties. These studies will be carried out primarily by undergraduate students from the University of Minnesota, Duluth.