RUI: Organic Chemistry of Hypervalent Compounds

在有机化学和高分子化学计划的支持下，明尼苏达大学德卢斯分校化学系的维克托·V·日丹金教授正在探索碘和氙气的高价化合物的化学。他的研究包括新的、稳定的高价碘和氙气与螯合氮配体的络合物的制备和结构表征，寻找利用高价碘的催化反应，开发基于苯并碘唑的新的氧化剂，以及制备、结构研究和探索混合的磷-碘叶立德和亚胺的反应性。通过这项本科院校的研究，有机和高分子化学计划支持明尼苏达大学德卢斯分校化学系的Viktor V.zhdankin教授的研究工作。通过对含碘或氙气化合物的新结构类型的研究，张丹金教授将加深我们对这些特殊化合物的结构和反应性的了解，开发用于有机合成的新试剂和新方法，并寻找具有特殊和有用性质的新化合物。来自明尼苏达大学、德卢斯大学和其他大学的本科生将进行这些研究。

With the support of the Organic and Macromolecular Chemistry Program, Professor Viktor V. Zhdankin, of the Department of Chemistry at the University of Minnesota, Duluth, is exploring the chemistry of hypervalent compounds of iodine and xenon. His studies include the preparation and structural characterization of novel, stable complexes of hypervalent iodine and xenon with chelating nitrogen ligands, a search for catalytic reactions utilizing hypervalent iodine, the development of new oxidizing agents based on benziodazoles, and the preparation, structural study, and exploration of the reactivity of mixed phosphonium-iodonium ylides and imides.With this Research in Undergraduate Institutions award, the Organic and Macromolecular Chemistry Program is supporting the research efforts of Professor Viktor V. Zhdankin, of the Department of Chemistry at the University of Minnesota, Duluth. Through the study of new structural types of compounds containing iodine or xenon, Professor Zhdankin will enhance our understanding of the structure and reactivity of these unusual compounds, develop new reagents and procedures for organic synthesis, and search for new compounds with unusual and useful properties. Undergraduate students from the University of Minnesota, Duluth and from other universities will carry out these studies.