CAREER: Metal-Ligand Multiple Bonding in Later, First Row Complexes

事业：后来的第一行复合物中的金属-配体多重键合

• 批准号: 0135057
• 负责人: Timothy Warren
• 金额: $ 51万
• 依托单位: Georgetown University
• 依托单位国家: 美国
• 项目类别: Continuing Grant
• 财政年份: 2002
• 资助国家: 美国
• 起止时间: 2002-02-01 至 2008-01-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=0135057&HistoricalAwards=false
• 关键词: CAREER; Metal; Ligand; Multiple; Bonding

Dr. Timothy Warren, Department of Chemistry, Georgetown University is supported by the Inorganic, Bioinorganic and Organometallic Chemistry program of the Division of Chemistry, National Science Foundation, for his work under a CAREER Award to establish a fundamental understanding of multiply-bound functional groups in later, first row complexes that participate in catalytic reactions involving cyclopropanation, aziridination and hydrocarbon oxidation. Dr. Warren will prepare carbene, nitrene and oxo complexes of Mn-Cu with a promising class of beta-diketiminate ligands in order to lend insight into these catalytic processes so as to enable the design of more efficient and selective catalysts.Dr. Warren has integrated research and education by developing a course, "Introduction to the Research Experience", that introduces motivated freshmen students to the research laboratory through a synthetic research project and plans to promote a better understanding of the scientific effort through a pilot outreach program to minority-serving DC high schools.

蒂莫西·沃伦，化学系，乔治城大学是由化学部，国家科学基金会的无机，生物无机和有机化学计划的支持下，他的工作在职业生涯奖，以建立一个基本的理解多重结合的官能团在后来，第一行复合物参与催化反应，涉及环丙烷化，氮丙啶化和烃氧化。 Warren博士将利用一类有前途的β-双烯酮亚胺配体制备Mn-Cu的卡宾、氮烯和氧代配合物，以便深入了解这些催化过程，从而能够设计出更有效和选择性更高的催化剂。Warren博士通过开发课程“研究经验介绍”，该计划通过一个综合研究项目将有动力的新生介绍给研究实验室，并计划通过一个试点外展计划向少数民族服务的DC高中促进对科学工作的更好理解。