NER: Directed-Assembly of Microscopic Wires from Semiconductor Nanoparticles

NER：半导体纳米粒子定向组装微观线

• 批准号: 0304413
• 负责人: Bret Flanders
• 金额: $ 4.73万
• 依托单位: Oklahoma State University
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 2003
• 资助国家: 美国
• 起止时间: 2003-06-01 至 2005-05-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=0304413&HistoricalAwards=false
• 关键词: NER; Directed; Assembly; Microscopic; Wires

Employing spontaneous assembly in the formation of targeted nanostructures holds promise as a revolutionary approach to shrinking the dimensions of electronic components down to (as low as) the diameter of the building block (~3nm). The objective of this particular application is to manipulate the phase behavior of 2D populations of semiconductor nanoparticles in order to form microscopic interconnects between arbitrarily chosen points in a circuit. This objective will be attained through the successful pursuit of the following aims: (1) To determine the dependence of the phase behavior on the experimental parameters (capping layer thickness and particle diameter), such that the degree to which dipolar interparticle interactions drive the spontaneous organization of these populations will be determined. (2) To dielectrophoretically induce the formation of microscopic wires of semiconductor nanoparticles between designated points in a simple circuit. As an outcome of the proposed investigations, we expect to have demonstrated that the experimental parameters can be adjusted so that microscopic interconnects spontaneously form between arbitrarily chosen points in a circuit. The research proposed in this application has the potential to solve the problem of interfacing a self-assembled, microscopic component with macroscopic electronics, thereby allowing for experimental evaluation of the electrical properties of the component. This characterization will be necessary in order to identify practical tasks to which the component can be fruitfully applied. It is also expected that determining the dependence of the phase behavior on the experimental parameters will generate quantitative insight into the interparticle potential-insight that will provide further guidance in designing, implementing, and improving methods for assembling targeted structures.

在目标纳米结构的形成中采用自发组装有望成为将电子元件的尺寸缩小到（低至）构建块的直径（~ 3 nm）的革命性方法。 该特定应用的目的是操纵半导体纳米颗粒的2D群体的相行为，以便在电路中的任意选择的点之间形成微观互连。 这一目标将通过以下目标的成功实现：（1）确定相行为对实验参数（覆盖层厚度和颗粒直径）的依赖性，从而确定偶极颗粒间相互作用驱动这些群体自发组织的程度。 (2)在一个简单的电路中，在指定的点之间诱导形成半导体纳米粒子的微观线。 作为拟议的调查结果，我们希望已经证明，实验参数可以调整，使微观互连电路中任意选择的点之间自发形成。 本申请中提出的研究有可能解决自组装的微观组件与宏观电子器件的接口问题，从而允许对组件的电性能进行实验评估。 为了确定该组成部分能够卓有成效地应用于哪些实际任务，这一特性是必要的。 还预计，确定相行为对实验参数的依赖性将产生对粒子间势的定量洞察，这将为设计、实施和改进组装目标结构的方法提供进一步的指导。