Modeling and Analysis of an Electrochemical Nanocell

电化学纳米电池的建模和分析

• 批准号: 0305577
• 负责人: Gerald Young
• 金额: $ 10万
• 依托单位: University of Akron
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 2003
• 资助国家: 美国
• 起止时间: 2003-07-15 至 2005-01-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=0305577&HistoricalAwards=false
• 关键词: Modeling; Analysis; Electrochemical; Nanocell

Proposal: DMS-0305577PI: Gerald W. Young [[e-mail]]Institution: University of AkronTitle: MODELING AND ANALYSIS OF AN ELECTROCHEMICAL NANOCELLABSTRACTThis project proposes to develop mathematical models for the electrochemical nanocell that forms during scanned probe oxidation. Scanned probe oxidation is a lithographic technique for producing nanoscale patterns on a substrate. These patterns have been employed successfully as an etch mask for wet and dry processes, and as chemical and biological templates. The increased demand for such high quality nanodevices requires better understanding of the growth processes involved in their fabrication. Although data on nanodeposition techniques have been collected over the past decade, investigators are only beginning to develop a qualitative picture of these processes, and are far from a complete quantitative understanding. The proposed research addresses both of these timely needs. Because of the varied and coupled physical phenomena involved (electromagnetic, chemical, thermal, etc.), the development of mathematical models for nanodeposition requires a team of individuals with complementary areas of expertise, and must proceed hand-in-hand with experimental validations. Such a team, consisting of interdisciplinary applied mathematicians, scientists and engineers is already active at The University of Akron and working in the area of nanomechanics and nanostructures. This team proposes to develop models for scanned probe oxidation that will, 1) explain experimental observations that are not well understood, and 2) suggest the range of parameters that is optimal for nanoscale growth. The team intends to develop appropriate solution and analysis procedures for these complex models, and test the validity of the models through comparison with experiments. The models will focus attention on the need to develop efficient solution strategies to solve complicated systems in the presence of noise. Further, the models developed in this work will lead to a significant number of problems in analysis. Questions on well-posedness, the use of similarity solutions, and bounds on solutions for the class of problems represented by the models will arise from the proposed efforts.This project proposes to develop mathematical models for the electrochemical nanocell that forms during scanned probe oxidation. Scanned probe oxidation is a critical technology for writing nanometer-size oxide patterns on the surface of a substrate. These oxide patterns can be used to prototype nanoscale masks, templates and devices. The proposed combination of modeling and experimental efforts will help to address the fundamental unanswered questions concerning the physics and chemistry of nanoscale structure formation and properties. In particular this project will provide the understanding necessary to control the height and width of oxide lines to produce precise nanoscale patterns. In addition to its impact on scientific research, this project will enhance graduate and undergraduate studies in the disciplines of mathematics, physics, chemistry, and engineering. Students participating in the program will, 1) be exposed tointerdisciplinary research involving sophisticated mathematical modeling and experiments, and 2) be trained to work within a multi-disciplinary environment. The educational training at both the graduate and undergraduate level will have a long-term impact on the mathematical sciences, providing students with exposure to a unique interdisciplinary environment and inspiring them to pursue careers in this cutting-edge area of national interest.

提案：DMS-0305577 PI：Gerald W. Young [www.example.com]机构：[e-mail]电化学纳米细胞结构的建模和分析本项目提出建立扫描探针氧化过程中形成的电化学纳米细胞的数学模型。 扫描探针氧化是用于在衬底上产生纳米级图案的光刻技术。 这些图案已成功地用作湿法和干法工艺的蚀刻掩模，以及化学和生物模板。 对此类高质量纳米器件的需求不断增加，需要更好地了解其制造过程中涉及的生长过程。 尽管在过去的十年中已经收集了关于纳米沉积技术的数据，但研究人员才刚刚开始对这些过程进行定性描述，而且还远远没有完全的定量理解。 拟议的研究解决了这两个及时的需求。 由于所涉及的各种物理现象（电磁、化学、热等），纳米沉积的数学模型的开发需要具有互补专业领域的个人团队，并且必须与实验验证携手进行。这样一个由跨学科应用数学家，科学家和工程师组成的团队已经活跃在阿克伦大学，并在纳米力学和纳米结构领域工作。 该团队建议开发扫描探针氧化模型，该模型将：1）解释尚不清楚的实验观察结果，2）建议最适合纳米级生长的参数范围。 该团队打算为这些复杂的模型开发适当的解决方案和分析程序，并通过与实验的比较来测试模型的有效性。 这些模型将集中注意力在需要制定有效的解决方案的策略，以解决复杂的系统中存在的噪声。 此外，在这项工作中开发的模型将导致大量的分析问题。 关于适定性的问题，使用相似的解决方案，并为模型所代表的一类问题的解决方案的界限将出现从拟议的effortes.This项目提出开发的电化学纳米细胞，在扫描探针氧化过程中形成的数学模型。 扫描探针氧化是在衬底表面写入纳米尺寸氧化物图案的关键技术。 这些氧化物图案可用于制作纳米级掩模、模板和器件的原型。 提出的建模和实验工作的结合将有助于解决有关纳米结构形成和性质的物理和化学的基本未回答的问题。 特别是这个项目将提供必要的理解，以控制氧化物线的高度和宽度，以产生精确的纳米级图案。 除了对科学研究的影响外，该项目还将加强数学、物理、化学和工程学科的研究生和本科生学习。 参加该计划的学生将，1）接触到涉及复杂的数学建模和实验的跨学科研究，2）接受培训，在多学科环境中工作。 研究生和本科阶段的教育培训将对数学科学产生长期影响，为学生提供独特的跨学科环境，并激励他们在这个国家利益的前沿领域追求职业生涯。