Development and Application of Self Patterned - Self Assembled Organic Monolayers on HOPG: Studying Nanoparticle Interactions in Controllable Geometries.

自图案化-自组装有机单层在 HOPG 上的开发和应用:研究可控几何形状中的纳米颗粒相互作用。

基本信息

  • 批准号:
    0616474
  • 负责人:
  • 金额:
    $ 41.6万
  • 依托单位:
  • 依托单位国家:
    美国
  • 项目类别:
    Continuing Grant
  • 财政年份:
    2006
  • 资助国家:
    美国
  • 起止时间:
    2006-08-15 至 2010-12-31
  • 项目状态:
    已结题

项目摘要

The intellectual objectives of this proposal are to develop strategies for spontaneous patterning of self-assembled monolayers prepared from organic molecules on highly oriented pyrolytic graphite, to use self-patterning, self-assembled monolayers to control assembly of single component and multi-component nanoparticles systems on HOPG and to explore the optical and magnetic properties of patterned nanoparticle systems as a function of composition and geometry. If successful, this will result in methods for spontaneous assembly of small nanoparticles on the small nanometer length scale. Professor Zimmt will use synthetic organic chemistry to design molecules that will permit deposition of patterned organic monolayers on graphite (HOPG). Linking metal and semiconductor nanoparticles to the organic layers can further functionalize the patterned monolayers. This work includes creation of 1,5-substituted anthracenes and triptycenes molecules that can be functionalized with linking groups, which in turn will bind metal or semiconductor nanoparticles. In this way, highly ordered arrays with perfectly spaced metal or semiconductor nanoparticle monolayers can be formed with full control over the interparticle spacing in the 1-4 nm range. Though many studies have been done on patterning of organic chains on clean surfaces, the synthetic chemistry introduced is highly creative, and will enable both specific control of surface patterns, as well as a detailed understanding of the properties that determine surface morphology.With this award, the Organic and Macromolecular Chemistry Program supports the research of Professor Matthew Zimmt of Brown University who will develop new methods that will allow fabrication of closely spaced structures for use in molecular electronics and nanotechnology and whose research will provide discipline-integrated training for graduate students and undergraduates.
该提案的智力目标是开发用于在高度定向热解石墨上由有机分子制备的自组装单层的自发图案化的策略,使用自图案化的自组装单层来控制单组分和多组分纳米颗粒系统在HOPG上的组装,并探索图案化的纳米颗粒系统作为组成和几何形状的函数的光学和磁性。如果成功,这将导致在小纳米长度尺度上自发组装小纳米颗粒的方法。Zimmt教授将使用合成有机化学来设计分子,使其能够在石墨(HOPG)上沉积图案化的有机单层。将金属和半导体纳米颗粒连接到有机层可以进一步使图案化的单层功能化。这项工作包括创造1,5-取代的蒽和三蝶烯分子,这些分子可以用连接基团官能化,从而结合金属或半导体纳米颗粒。以这种方式,可以形成具有完美间隔的金属或半导体纳米颗粒单层的高度有序的阵列,并完全控制1-4 nm范围内的颗粒间间距。虽然许多研究都是关于清洁表面上有机链的图案化,但引入的合成化学具有高度的创造性,可以实现对表面图案的特定控制,以及对决定表面形态的属性的详细理解。有机和高分子化学计划支持布朗大学的马修·齐姆特教授的研究,他将开发新的方法,它允许制造用于分子电子学和纳米技术的密集结构,其研究将为研究生和本科生提供学科综合培训。

项目成果

期刊论文数量(0)
专著数量(0)
科研奖励数量(0)
会议论文数量(0)
专利数量(0)

数据更新时间:{{ journalArticles.updateTime }}

{{ item.title }}
{{ item.translation_title }}
  • DOI:
    {{ item.doi }}
  • 发表时间:
    {{ item.publish_year }}
  • 期刊:
  • 影响因子:
    {{ item.factor }}
  • 作者:
    {{ item.authors }}
  • 通讯作者:
    {{ item.author }}

数据更新时间:{{ journalArticles.updateTime }}

{{ item.title }}
  • 作者:
    {{ item.author }}

数据更新时间:{{ monograph.updateTime }}

{{ item.title }}
  • 作者:
    {{ item.author }}

数据更新时间:{{ sciAawards.updateTime }}

{{ item.title }}
  • 作者:
    {{ item.author }}

数据更新时间:{{ conferencePapers.updateTime }}

{{ item.title }}
  • 作者:
    {{ item.author }}

数据更新时间:{{ patent.updateTime }}

Matthew Zimmt其他文献

Matthew Zimmt的其他文献

{{ item.title }}
{{ item.translation_title }}
  • DOI:
    {{ item.doi }}
  • 发表时间:
    {{ item.publish_year }}
  • 期刊:
  • 影响因子:
    {{ item.factor }}
  • 作者:
    {{ item.authors }}
  • 通讯作者:
    {{ item.author }}

{{ truncateString('Matthew Zimmt', 18)}}的其他基金

1D and 2D Cross-Linking of Patterned Monolayers: From Molecules to Reactive Templates
图案单层的一维和二维交联:从分子到反应模板
  • 批准号:
    1607273
  • 财政年份:
    2016
  • 资助金额:
    $ 41.6万
  • 项目类别:
    Standard Grant
1-D and 2-D Patterning of Strongly Physisorbed Monolayers on HOPG: Strategies and Template Applications
HOPG 上强物理吸附单层的一维和二维图案化:策略和模板应用
  • 批准号:
    1058241
  • 财政年份:
    2011
  • 资助金额:
    $ 41.6万
  • 项目类别:
    Continuing Grant
Functional Architectures for Electron Transfer in Solution and on Electrodes
溶液中和电极上电子转移的功能架构
  • 批准号:
    0108945
  • 财政年份:
    2001
  • 资助金额:
    $ 41.6万
  • 项目类别:
    Continuing Grant
Travel Grant Application for U.S. Scientists to Attend the XVIIth IUPAC Symposium on Photochemistry
美国科学家参加第十七届 IUPAC 光化学研讨会的旅费补助申请
  • 批准号:
    9812659
  • 财政年份:
    1998
  • 资助金额:
    $ 41.6万
  • 项目类别:
    Standard Grant
Exploration of Solvent Mediated Electronic Coupling in Electron Transfer and Energy Transfer Reactions
电子转移和能量转移反应中溶剂介导的电子偶联探索
  • 批准号:
    9708351
  • 财政年份:
    1997
  • 资助金额:
    $ 41.6万
  • 项目类别:
    Continuing Grant
Kinetic and Thermodynamic Studies of Long Distance Electron Transfer Reactions
长距离电子转移反应的动力学和热力学研究
  • 批准号:
    9206765
  • 财政年份:
    1992
  • 资助金额:
    $ 41.6万
  • 项目类别:
    Continuing Grant
Structural Dependences of Long Distance Electron Transfer Reactions
长距离电子转移反应的结构依赖性
  • 批准号:
    8820741
  • 财政年份:
    1989
  • 资助金额:
    $ 41.6万
  • 项目类别:
    Continuing Grant
Presidential Young Investigator/Photochemical and Photophysical Electron Transfer Studies
总统青年研究员/光化学和光物理电子转移研究
  • 批准号:
    8957387
  • 财政年份:
    1989
  • 资助金额:
    $ 41.6万
  • 项目类别:
    Continuing Grant

相似国自然基金

Graphon mean field games with partial observation and application to failure detection in distributed systems
  • 批准号:
  • 批准年份:
    2025
  • 资助金额:
    0.0 万元
  • 项目类别:
    省市级项目

相似海外基金

Development and evaluation of a smartphone application to promote the use of alcoholism Self-help groups
开发和评估智能手机应用程序以促进酗酒自助团体的使用
  • 批准号:
    23K02994
  • 财政年份:
    2023
  • 资助金额:
    $ 41.6万
  • 项目类别:
    Grant-in-Aid for Scientific Research (C)
Development of surface-emitting broadband swept-source using self-assembled InAs quantum dots and its application for OCT
自组装InAs量子点面发射宽带扫频源的研制及其在OCT中的应用
  • 批准号:
    23H01449
  • 财政年份:
    2023
  • 资助金额:
    $ 41.6万
  • 项目类别:
    Grant-in-Aid for Scientific Research (B)
Development and effectiveness of LAICA, a self-care application to increase self-esteem in adolescents
LAICA(一种提高青少年自尊的自我护理应用程序)的开发和有效性
  • 批准号:
    23K02642
  • 财政年份:
    2023
  • 资助金额:
    $ 41.6万
  • 项目类别:
    Grant-in-Aid for Scientific Research (C)
Elements: Development of cyberinfrastructure to establish a scalable application of self-supervised machine learning for over a decade of NOAA's water column sonar data
要素:开发网络基础设施,以建立可扩展的自监督机器学习应用程序,用于 NOAA 十多年来的水柱声纳数据
  • 批准号:
    2311843
  • 财政年份:
    2023
  • 资助金额:
    $ 41.6万
  • 项目类别:
    Standard Grant
Development of self-management application for PMS and verification of its effectiveness
PMS自我管理应用程序开发及有效性验证
  • 批准号:
    22K10938
  • 财政年份:
    2022
  • 资助金额:
    $ 41.6万
  • 项目类别:
    Grant-in-Aid for Scientific Research (C)
Development of the Japanese version of the Self-Stigam of Stuttering Scale and its clinical application
日本版口吃自我Stigam量表的研制及其临床应用
  • 批准号:
    21K17523
  • 财政年份:
    2021
  • 资助金额:
    $ 41.6万
  • 项目类别:
    Grant-in-Aid for Early-Career Scientists
Development of an application for self-cognitive change to reduce stress caused by human relationships
开发自我认知改变应用程序,以减轻人际关系造成的压力
  • 批准号:
    21K12197
  • 财政年份:
    2021
  • 资助金额:
    $ 41.6万
  • 项目类别:
    Grant-in-Aid for Scientific Research (C)
Development, Usability Evaluation, and Pilot Feasibility Study of an mHealth Application Supporting Self-Management of Accidental Bowel Leakage, "I'M ABLe"
支持意外肠漏自我管理的移动医疗应用程序的开发、可用性评估和试点可行性研究,“IM ABLe”
  • 批准号:
    10322031
  • 财政年份:
    2020
  • 资助金额:
    $ 41.6万
  • 项目类别:
Development of self-assembly prodrug: Application to the cancer therapy by reset of immune-cycle
自组装前药的开发:通过重置免疫循环在癌症治疗中的应用
  • 批准号:
    20H00657
  • 财政年份:
    2020
  • 资助金额:
    $ 41.6万
  • 项目类别:
    Grant-in-Aid for Scientific Research (A)
Development of self-organizing 3D nanoporous structures and application to high-performance heat transfer surface
自组织3D纳米多孔结构的开发及其在高性能传热表面的应用
  • 批准号:
    19K14918
  • 财政年份:
    2019
  • 资助金额:
    $ 41.6万
  • 项目类别:
    Grant-in-Aid for Early-Career Scientists
{{ showInfoDetail.title }}

作者:{{ showInfoDetail.author }}

知道了