Molecular Metal Complexes as Defined Spin Impurities for Kondo Physics

分子金属络合物作为近藤物理学定义的自旋杂质

• 批准号: 17792946
• 负责人: Professor Dr. Heiko B. Weber
• 金额: --
• 依托单位: Lehrstuhl für Angewandte Physik (LAP)
• 依托单位国家: 德国
• 项目类别: Research Grants
• 财政年份: 2005
• 资助国家: 德国
• 起止时间: 2004-12-31 至 2008-12-31
• 项目状态: 已结题
• 来源: https://gepris.dfg.de/gepris/projekt/17792946?language=en
• 关键词: Molecular; Metal; Complexes; Defined; Spin

The interaction of molecules with metals has recently attracted increasing attention due to the appearance of molecular electronics as a candidate for future nanoelectronics. In this project, we will create and investigate systems where a molecule carries an unpaired spin. We propose to investigate two types of interaction between the spin degree of freedom and the conduction electrons in the metal: The first experiment is dedicated to the dynamical screening of the spin degree of freedom by the conduction electrons of the metal, a phenomenon which is closely related to the Kondo effect known in solid state metals with magnetic impurities. For that purpose, we will immobilize spin-bearing coordination compounds (e.g. FeII and CoII compounds) in single-molecule junctions. Thereby, the main observable parameter will be the I/V dependence of a current passing through the spin-bearing molecule. Second, we will investigate binuclear compounds with two spin degrees of freedom. Here, more complicated variations of Kondo physics can be explored. As a further reaching goal (and presumably beyond the two-year period for this grant), this research will guide towards Spintronics on the single-molecule level, where the electron transport can be controlled by the relative orientation of the two spins. The requirements to the molecules and the experiment are delicate and imperatively need a close cooperation between synthetic chemistry and experimental physics.

由于分子电子学作为未来纳米电子学的一个候选领域的出现，分子与金属的相互作用近年来引起了越来越多的关注。在这个项目中，我们将创建和研究分子携带未配对自旋的系统。我们建议研究金属中自旋自由度与传导电子之间的两种相互作用：第一个实验致力于金属的传导电子对自旋自由度的动态筛选，这一现象与已知的具有磁性杂质的固态金属中的近藤效应密切相关。为此，我们将在单分子连接处固定带有自旋的配位化合物（例如FeII和CoII化合物）。因此，主要的可观测参数将是通过含自旋分子的电流的I/V依赖性。其次，我们将研究具有两个自旋自由度的双核化合物。在这里，可以探索更复杂的近藤物理变化。作为进一步达到的目标（大概超过两年的资助期），这项研究将引导单分子水平的自旋电子学，其中电子传输可以通过两个自旋的相对方向来控制。对分子和实验的要求是微妙的，迫切需要合成化学和实验物理的密切合作。