Magnetic Nanoparticle Interactions: From Magnetostatics to Exchange

磁性纳米粒子相互作用：从静磁到交换

• 批准号: 0804779
• 负责人: Sara Majetich
• 金额: $ 30万
• 依托单位: Carnegie-Mellon University
• 依托单位国家: 美国
• 项目类别: Continuing Grant
• 财政年份: 2008
• 资助国家: 美国
• 起止时间: 2008-07-01 至 2012-06-30
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=0804779&HistoricalAwards=false
• 关键词: Magnetic; Nanoparticle; Interactions; Magnetostatics; Exchange

TECHNICAL: Surfactant-coated nanoparticles have tremendous advantages due to their monodispersity and ability to form ordered arrays. Nanoscale magnetic measurements have demonstrated that uniformity in the particle size and spacing affects the collective dynamical response and the length scale of magnetic order. The surfactant controls the particle size distribution and provides mobility needed for self-assembly, but it also limits the range of interesting magnetic nanostructures that can be prepared. The typical 2-4 nm separation between cores means that interparticle coupling is almost purely magnetostatic. The surfactant provides at best a temporary, semi-permeable barrier to oxidation of materials such as iron and cobalt. Assemblies have the mechanical consistency of wax, making them unsuitable for most device applications. The surfactant makes it difficult to achieve good electrical contact, and varying amounts of surface coverage causes particle-to-particle differences in the apparent tunneling barriers. The project explores processing methods to prepare monodisperse metallic nanopillars in ordered arrays. The pillars will be made by reactive ion etching (RIE) a nanoparticle mask. In the simpler form the mask will be nonmagnetic and the magnetic particles will be created by sputter deposition on top of the dense pillar array. Direct patterning of magnetic multilayers with high density methanol-based plasma RIE will also be investigated to determine the minimum feature size and the effect of this dry etching process on magnetic response. The research focuses on systems where magnetic imaging and neutron reflectivity techniques will reveal temperature and field-dependent magnetic correlation lengths, which provides a deeper understanding of magnetic nanoparticle interactions. Manganese phosphide has a first order ferromagnetic to paramagnetic transition, so that the strength of magnetostatic interactions between MnP nanoparticles should change sharply with temperature. Ferromagnetic Co nanoparticles coupled to an antiferromagnetic (AF) IrMn layer may show differences in collective correlations due to exchange bias effects, depending on the AF domain size. Model soft nanocrystalline materials, with Fe pillars in a FeBSi matrix, will also be used to test the degree of exchange coupling between the nanoparticles in the array, which should change abruptly at the Curie temperature of the matrix, enabling quantitative comparison of exchange and magnetostatic contributions to the composite material. Finally the RIE of magnetic materials will be used to prepare some multilayer nanopillars where the small feature size leads to novel quantum confinement and spin accumulation effects. The intellectual merit of this project is in the development of a versatile, scalable process to prepare uniform magnetic nanoparticles and nanoparticle arrays in an inorganic matrix. The nanoscale characterization tools will reveal new features concerning the development of long-range magnetic order, and will clarify the interpretation of macroscopic measurements. NON-TECHNICAL: The work will have broad impact in numerous ways. It will form the thesis project for a graduate student and undergraduate research projects for several students. Hands-on demonstrations and laboratory experiments related to the magnetic phase transition in MnP will be developed for middle school students, and undergraduate physics laboratories. This project is jointly supported by DMR?s Metals program and Condensed Matter Physics program.

技术：表面活性剂包覆的纳米颗粒具有巨大的优势，因为它们具有单分散性和形成有序阵列的能力。纳米尺度的磁性测量表明，颗粒尺寸和间距的均匀性影响集体动力学响应和磁序的长度尺度。表面活性剂控制颗粒尺寸分布并提供自组装所需的流动性，但它也限制了可以制备的有趣的磁性纳米结构的范围。核之间典型的2-4 nm间隔意味着粒子间耦合几乎是纯静磁的。表面活性剂最多提供暂时的、半渗透的屏障以防止材料如铁和钴的氧化。组件具有蜡的机械一致性，使其不适合大多数设备应用。表面活性剂使得难以实现良好的电接触，并且不同量的表面覆盖导致表观隧穿势垒的颗粒间差异。该项目探索了制备有序阵列的单分散金属纳米柱的加工方法。这些柱子将通过反应离子蚀刻（RIE）纳米颗粒掩模制成。在更简单的形式中，掩模将被蚀刻，并且磁性颗粒将通过在密集柱阵列的顶部上的溅射沉积来产生。磁性多层膜与高密度甲醇基等离子体RIE的直接图案化也将进行研究，以确定最小的特征尺寸和这种干法蚀刻工艺对磁响应的影响。该研究的重点是磁成像和中子反射率技术将揭示温度和场依赖的磁相关长度的系统，这提供了对磁性纳米颗粒相互作用的更深入理解。磷化锰具有一级铁磁到顺磁的转变，使得MnP纳米颗粒之间的静磁相互作用的强度应随温度急剧变化。铁磁Co纳米粒子耦合到反铁磁（AF）IrMn层可能会显示由于交换偏置效应的集体相关性的差异，这取决于AF域的大小。模型软纳米晶材料，在FeBSi矩阵中的Fe柱，也将用于测试阵列中的纳米颗粒之间的交换耦合程度，这应该在基体的居里温度下突然改变，从而能够定量比较对复合材料的交换和静磁贡献。最后，磁性材料的反应离子刻蚀将被用于制备一些多层纳米柱，其中小的特征尺寸导致新的量子限制和自旋累积效应。该项目的智力价值在于开发一种通用的、可扩展的工艺，以在无机基质中制备均匀的磁性纳米颗粒和纳米颗粒阵列。纳米表征工具将揭示有关长程磁序发展的新特征，并将阐明宏观测量的解释。非技术性：这项工作将在许多方面产生广泛的影响。它将形成一个研究生的论文项目和几个学生的本科研究项目。与MnP中磁相变相关的动手演示和实验室实验将为中学生和本科物理实验室开发。该项目由DMR？的金属程序和凝聚态物理程序。