NSF/DMR-BSF: Origin of Large Electromechanical Response in Non-Classical Electrostrictors

NSF/DMR-BSF：非经典电致伸缩器大机电响应的起源

• 批准号: 1701747
• 负责人: Anatoly Frenkel
• 金额: $ 44.38万
• 依托单位: SUNY at Stony Brook
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 2016
• 资助国家: 美国
• 起止时间: 2016-11-01 至 2019-12-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=1701747&HistoricalAwards=false
• 关键词: NSF; DMR; BSF; Origin; Large

NON-TECHNICAL DESCRIPTION: Materials with strong mechanical response to applied electric field are of great importance for a wide range of applications ranging from actuators for portable cameras to transducers for audio-speakers and sonars. Since discovery of a giant electromechanical response in gadolinium-doped cerium oxides in 2012, this material is considered as a new type of ceramic that generates strain due to a small fraction of their structural units, called electromechanically "active". The main challenge towards understanding this mechanism and rational designing new electromechanical materials with the desired response has been the inability to decipher atomic architecture of these units and "catch them in action", that is, to take a snapshot of these units while the strain is generated under electric field. In order to fully characterize the structure of active units "in action", the investigators are studying thin film doped cerium oxide ceramics under electric field by high energy resolution methods (such as X-ray absorption spectroscopy) and modeling the results by advanced theoretical methods. The project impacts the field of ceramic materials through the development of fundamental understanding and design criteria for this new class of electromechanical materials. The project fosters international ties between Yeshiva University in New York and Weizmann Institute of Science in Rehovot, Israel. The broader impacts of this project are realized through establishing connections between faculty and students from both institutions, and in engaging underrepresented groups (such as women) in science and engineering disciplines. TECHNICAL DETAILS: Thin films of cerium oxide that have trivalent metal impurities possess intriguing structural, electric and mechanical properties, including ionic conductivity, non-linear elastic effects and strong mechanical stresses in response to the application of electric field. Anatoly Frenkel (SUNY at Stony Brook), his international collaborator Igor Lubomirsky (Weizmann Institute of Science) and their respective groups are working to understand the mechanisms of electrostriction (a particularly large electromechanical response that is quadratic with electric field). The investigators strive to answer such fundamental questions as the effects of impurities on the generation of strain and stress in the lattice. They are applying advanced methods of X-ray absorption spectroscopy with high energy resolution in situ, under applied field, to identify the active species - cations that are located in the distorted units - in order to understand, in detail, the behavior of these units and their role in the electrostriction. Data analysis is being carried out by modeling structural distortions theoretically and comparing their simulated X-ray absorption spectra with experimental ones. This project offers research opportunities and training at advanced national research facilities at the post-graduate, graduate and undergraduate levels with significant inclusion of underrepresented female students.

非技术描述：对外加电场具有强机械响应的材料对于从便携式相机的致动器到音频扬声器和声纳的换能器的广泛应用具有重要意义。自2012年在掺钆氧化铈中发现巨大的机电响应以来，这种材料被认为是一种新型陶瓷，由于其结构单元的一小部分而产生应变，称为机电“活性”。理解这种机制和合理设计具有所需响应的新机电材料的主要挑战是无法破译这些单元的原子结构并“捕捉它们的作用”，即在电场下产生应变时拍摄这些单元的快照。为了充分表征“作用中”活性单元的结构，研究人员正在通过高能量分辨率方法（如X射线吸收光谱）研究电场下的薄膜掺杂氧化铈陶瓷，并通过先进的理论方法对结果进行建模。该项目通过对这类新的机电材料的基本理解和设计标准的发展影响陶瓷材料领域。该项目促进了纽约的叶史瓦大学和以色列Rehovalian的魏茨曼科学研究所之间的国际联系。该项目的更广泛的影响是通过建立教师和学生从两个机构之间的联系，并在从事科学和工程学科的代表性不足的群体（如妇女）实现。技术规格：含有三价金属杂质的氧化铈薄膜具有令人感兴趣的结构、电学和机械性能，包括离子导电性、非线性弹性效应和响应于施加电场的强机械应力。Anatoly Frenkel（纽约州立大学斯托尼布鲁克分校），他的国际合作者Igor Lubomirsky（魏茨曼科学研究所）和他们各自的小组正在努力了解电致伸缩（一种与电场成二次方的特别大的机电响应）的机制。研究人员致力于回答诸如杂质对晶格中应变和应力产生的影响等基本问题。他们正在应用具有高能量分辨率的X射线吸收光谱的先进方法，在施加的电场下，识别活性物质-位于扭曲单元中的阳离子-以详细了解这些单元的行为及其在电致伸缩中的作用。数据分析正在进行理论建模结构扭曲和比较其模拟的X射线吸收光谱与实验的。该项目为研究生、研究生和本科生提供了在先进的国家研究设施进行研究和培训的机会，其中包括大量代表性不足的女生。