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Accomplishment Based Renewal: An experimental study of phase separation and mineral fluid equilibria on iron and hydrogen transport in mid-ocean ridge hydrothermal systems

基于成就的更新：洋中脊热液系统中铁和氢传输的相分离和矿物流体平衡的实验研究

基本信息

批准号：
1736679
负责人：
William Seyfried
金额：
$ 43.1万
依托单位：
University of Minnesota-Twin Cities
依托单位国家：
美国
项目类别：
Standard Grant
财政年份：
2017
资助国家：
美国
起止时间：
2017-08-15 至 2023-07-31
项目状态：
已结题

来源：
https://www.nsf.gov/awardsearch/showAward?AWD_ID=1736679&HistoricalAwards=false
关键词：
Accomplishment Based Renewal experimental study

项目摘要

Hydrothermal circulation at mid-ocean ridges constitutes the largest geothermal system on Earth. Venting of spectacular plumes of hot, metal-bearing, fluid into seawater from sulfide structures on the seafloor along the volcanically active global mid-ocean ridge system is the end result of heat and chemical transfer between the ocean crust and the overlying ocean. As a result, the composition of seafloor hydrothermal vent fluids places a major control on ocean chemistry, as it has throughout Earth history. Seafloor hydrothermal fluids also provide dissolved gases and other chemicals to sustain microbial ecosystems that provide clues to the origin of life on Earth. The discovery of submarine hydrothermal venting and their accompanying microbial communities that do not require sunlight or organic matter created by photosynthesis to live, remains one of the most significant discoveries in modern science. The mechanisms, however, by which seawater is transformed to compositionally distinct hydrothermal vent fluids are uncertain, owing to the extreme temperatures and pressures of these processes. This research uses novel laboratory reactor and in-situ sensor systems to carry out first-of-a-kind experiments at the temperatures and pressures of seafloor hydrothermal venting to determine the effect of oxidation-reduction reactions and pH on mineral solubility at temperatures and pressure not previously studied. Goals of the work are to provide fundamental geochemical thermodynamic and kinetic parameters involving iron and hydrogen in water-rock interaction at high temperatures and pressures. The broader impacts of the work to research and science education include (1) Involvement of undergraduate science majors; (2) graduate student training in experimental and theoretical studies of mineral-fluid reaction which enhances their career opportunities; (3) development of new models to predict more accurately the links between the physical and chemical processes in natural multi-component hydrothermal systems; (4) physical infrastructure enhancement with the development of new equipment and techniques to conduct experiments and collect data in the area of phase separation of H2O; and, (5) public outreach in cooperation with K-12 programs at the Bell Museum of Natural History at the University of Minnesota. This research will acquire data to advance knowledge of mineral-fluid reactions that control the chemical evolution of mid-ocean ridge hydrothermal fluids. The experiments specifically address changes in dissolved Fe and H2 in fluids coexisting with mineral buffers at temperatures and pressures sufficient to cause phase separation in the NaCl-H2O system. The research will examine the possibility that fixing dissolved Fe and H2 in mineral-buffered reactions increases the solubility of these components in both fluid phases. This strategy contrasts sharply with previous fluid-only phase separation experiments where the inventory of dissolved Fe was limited. High Fe/Cl and Fe/Mn ratios and high dissolved H2 and H2S concentrations in vapor-rich vent fluids at mid-ocean ridges, especially in the aftermath of magmatic activity, implicate mineral buffering. Thus, the results of this experimental work will provide quantitative rigor to the presently qualitative observations of the temporal evolution of hydrothermal vent fluids at subseafloor temperatures approaching 500°C. These high temperature fluids have some of the highest dissolved Fe and H2 concentrations yet reported; but, in the absence of the experimental data, are difficult to interpret unambiguously in terms of subseafloor redox and pH controlling reactions. Scientific implications of the research will enable the development of theoretically-based predictive approaches for modeling aqueous speciation and mineral solubility in the low density and two-phase regions in the NaCl-H2O system. These conditions also apply to many continental hydrothermal systems. These terrestrial systems have immense scientific, economic, and practical significance and have critical importance to the Earth's thermal budget and geochemical cycles.

洋中脊的热液循环构成了地球上最大的地热系统。沿着火山活跃的全球大洋中脊系统，海底的硫化物结构将含金属的热流体喷出壮观的羽流，进入海水中，这是海洋地壳与上覆海洋之间热量和化学传递的最终结果。因此，海底热液喷口流体的组成对海洋化学起着重要的控制作用，就像它在整个地球历史上所起的作用一样。海底热液还提供溶解气体和其他化学物质来维持微生物生态系统，为地球上生命的起源提供线索。海底热液喷口的发现及其伴随的微生物群落不需要阳光或光合作用产生的有机物就能生存，这仍然是现代科学中最重要的发现之一。然而，由于这些过程的极端温度和压力，海水转化为成分不同的热液喷口流体的机制尚不确定。本研究使用新型实验室反应器和原位传感器系统，在海底热液喷口的温度和压力下进行了首次同类实验，以确定氧化还原反应和pH值对温度和压力下矿物溶解度的影响。研究的目的是提供高温高压下铁和氢在水岩相互作用中的基本地球化学热力学和动力学参数。这项工作对科研和科学教育的广泛影响包括：(1)本科理科生的参与；(2)培养研究生进行矿液反应的实验和理论研究，增加其就业机会；(3)建立新的模型，更准确地预测自然多组分热液系统的物理和化学过程之间的联系；(4)随着新设备和新技术的发展，在H2O相分离领域进行实验和数据收集的物理基础设施得到加强；(5)与明尼苏达大学贝尔自然历史博物馆的K-12项目合作开展公众宣传。这项研究将获得数据，以提高对控制中洋脊热液化学演化的矿物-流体反应的认识。实验专门研究了在温度和压力足以导致NaCl-H2O体系相分离的情况下，与矿物缓冲液共存的流体中溶解的Fe和H2的变化。该研究将检验在矿物缓冲反应中固定溶解的铁和氢增加这些成分在两种流体相中的溶解度的可能性。这种策略与以前的纯流体相分离实验形成鲜明对比，其中溶解铁的库存是有限的。洋中脊富气喷口流体中高Fe/Cl和Fe/Mn比值以及高溶解H2和H2S浓度，特别是在岩浆活动之后，暗示了矿物缓冲作用。因此，这项实验工作的结果将为目前对海底温度接近500°C时热液喷口流体时间演化的定性观测提供定量的严密性。这些高温流体的溶解铁和氢浓度是目前报道的最高的；但是，在缺乏实验数据的情况下，很难明确地解释海底氧化还原和pH控制反应。该研究的科学意义将使基于理论的预测方法的发展成为可能，用于模拟NaCl-H2O体系中低密度和两相区域的水形态和矿物溶解度。这些条件也适用于许多大陆热液系统。这些陆地系统具有巨大的科学、经济和实际意义，对地球的热收支和地球化学循环至关重要。