CAREER: Rational Design and Manufacturing of Nanostructured Surfaces and Interfaces in Lightweight Materials

职业：轻质材料纳米结构表面和界面的合理设计和制造

• 批准号: 1751590
• 负责人: Neil Dasgupta
• 金额: $ 50万
• 依托单位: Regents of the University of Michigan - Ann Arbor
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 2018
• 资助国家: 美国
• 起止时间: 2018-06-01 至 2024-05-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=1751590&HistoricalAwards=false
• 关键词: CAREER; Rational; Design; Manufacturing; Nanostructured

This Faculty Early Career Development Program (CAREER) award supports fundamental research on scalable manufacturing of lightweight structural materials including polymer-matrix composites and lightweight magnesium alloys. The grant looks to develop new surface modification techniques, relying on atomic layer deposition (ALD) which can deposit sub-monolayer thick layers which serve as seeds to subsequently grow new structures three-dimensional structures at the nanoscale. These designed nanostructures are remarkably versatile. They can serve to improve the strength of polymer composites allowing for light-weight materials as well as impede corrosion on metal surfaces. This addresses critical needs, for example, in the transportation sector to improve fuel efficiency and vehicle performance, while maintaining safety. Beyond the direct impact on lightweighting, the scientific knowledge generated will provide an alternative design paradigm to the bottom-up design and manufacturing at the nanoscale. The educational goal is to promote public awareness of the importance of nanomaterials for the future of domestic manufacturing. The educational plan integrates concepts of design and manufacturing, nanotechnology, and surface science across multiple levels, including a new 6th grade materials curriculum, integrating materials education into undergraduate student team mentorship, and promoting a more diverse STEM workforce through research demonstrations to encourage underrepresented students to apply to graduate school and participate in research.Current manufacturing processes for controlling surface and interfacial structure in bulk structural materials suffer from poor control of geometric parameters such as feature size, shape, geometric orientation, which is particularly challenging within hierarchical assemblies of nanomaterials on non-planar surfaces. This lack of deterministic control of structure limits our ability to fundamentally understand how the nanostructuring produces specific material properties and a route to rationally design optimized structures to achieve application-specific properties. This project's effort addresses this limitation by quantitatively identifying the process-structure relationships needed to achieve deterministic control of interfacial geometry and composition at the nanoscale. The approach uses the concept of spatial ALD to generate sub-monolayer seeding areas for the growth of nanostructures through solution-based processes. The process can be repeated to develop three dimensional nanostructures on surfaces to precisely tune the interfacial geometry, composition, and microstructure of lightweight structural materials, and quantify the impact on their mechanical properties and corrosion resistance. An improved understanding of these process-structure relationships will provide the fundamental knowledge needed to ?encode? the manufacturing instructions for the controlled hierarchical assembly of nanoscale building blocks into surface architectures. This approach will be used to address two critical challenges in lightweight structural materials: 1) rational design of nanostructured interphases in polymer matrix composites to tune their mechanical properties, and 2) improving corrosion-resistance of magnesium alloys.This award reflects NSF's statutory mission and has been deemed worthy of support through evaluation using the Foundation's intellectual merit and broader impacts review criteria.

该学院早期职业发展计划（CAREER）奖支持轻质结构材料（包括聚合物基复合材料和轻质镁合金）的可扩展制造的基础研究。该资助旨在开发新的表面改性技术，依赖于原子层沉积（ALD），该技术可以存款亚单层厚层，这些厚层作为种子，随后在纳米级生长新的结构三维结构。这些设计的纳米结构非常通用。它们可以用于提高聚合物复合材料的强度，允许轻质材料以及阻止金属表面的腐蚀。这解决了交通部门的关键需求，例如提高燃油效率和车辆性能，同时保持安全性。除了对轻量化的直接影响外，所产生的科学知识将为纳米级自下而上的设计和制造提供另一种设计范式。教育目标是提高公众对纳米材料对未来国内制造业的重要性的认识。 该教育计划将设计和制造，纳米技术和表面科学的概念整合到多个层面，包括新的六年级材料课程，将材料教育融入本科生团队指导，并通过研究示范促进更多样化的STEM劳动力，以鼓励代表性不足的学生申请研究生院并参与研究。块体结构材料中界面结构遭受几何参数如特征尺寸、形状、几何取向的不良控制，这在非平面表面上的纳米材料的分级组件中是特别具有挑战性的。这种结构的确定性控制的缺乏限制了我们从根本上理解纳米结构化如何产生特定材料特性的能力，以及合理设计优化结构以实现特定应用特性的途径。该项目的努力解决了这一限制，通过定量识别的过程中所需的结构关系，以实现确定性的控制界面的几何形状和组成在纳米级。该方法使用空间ALD的概念，通过基于溶液的工艺产生用于纳米结构生长的亚单层播种区域。该过程可以重复进行，以在表面上形成三维纳米结构，从而精确调整轻质结构材料的界面几何形状、组成和微观结构，并量化对其机械性能和耐腐蚀性的影响。对这些过程-结构关系的更好理解将提供所需的基本知识？编码？用于将纳米级构建块受控分级组装成表面结构的制造说明。这一方法将用于解决轻质结构材料的两个关键挑战：1）合理设计聚合物基复合材料中的纳米结构界面，以调整其机械性能; 2）提高镁合金的耐腐蚀性。该奖项反映了NSF的法定使命，并通过使用基金会的知识价值和更广泛的影响审查标准进行评估，被认为值得支持。

项目成果

Sodium mechanics: Effects of temperature, strain rate, and grain rotation and implications for sodium metal batteries

• DOI: 10.1016/j.eml.2022.101644
• 发表时间: 2022-02
• 期刊: Extreme Mechanics Letters
• 影响因子: 4.7
• 作者: W. LePage;Yuxin Chen;A. Poli;M. Thouless;N. Dasgupta

Tunable Sulfur Incorporation into Atomic Layer Deposition Films Using Solution Anion Exchange

• DOI: 10.1021/acs.chemmater.2c03773
• 发表时间: 2023-03-17
• 期刊: CHEMISTRY OF MATERIALS
• 影响因子: 8.6
• 作者: Lenef，Julia D.;Gayle，Andrew J.;Dasgupta，Neil P.
• 通讯作者: Dasgupta，Neil P.

Tunable Atomic Layer Deposition into Ultra-High-Aspect-Ratio (>60000:1) Aerogel Monoliths Enabled by Transport Modeling

• DOI: 10.1021/acs.chemmater.1c00770
• 发表时间: 2021-07
• 期刊: Chemistry of Materials
• 影响因子: 8.6
• 作者: Andrew J. Gayle;Zachary J. Berquist;Yuxin Chen;Alexander J. Hill;Jacob Y. Hoffman;Ashley R. Bielinski;A. Lenert;N. Dasgupta

Lithium Mechanics: Roles of Strain Rate and Temperature and Implications for Lithium Metal Batteries

• DOI: 10.1149/2.0221902jes
• 发表时间: 2019-01-08
• 期刊: JOURNAL OF THE ELECTROCHEMICAL SOCIETY
• 影响因子: 3.9
• 作者: LePage, William S.;Chen, Yuxin;Dasgupta, Neil P.
• 通讯作者: Dasgupta, Neil P.

Rational Design of Transparent Nanowire Architectures with Tunable Geometries for Preventing Marine Fouling

• DOI: 10.1002/admi.202000672
• 发表时间: 2020-07
• 期刊: Advanced Materials Interfaces
• 影响因子: 5.4
• 作者: Jing Wang;Sudarat Lee;Ashley R. Bielinski;K. Meyer;Abhishek Dhyani;Alondra M. Ortiz-Ortiz-Alondra-M.-Ortiz-Ortiz-2005015126;A. Tuteja;N. Dasgupta