Quantifying the Coarsening Kinetics of Supported Metal Nanoparticles Using Time-resolved Electron Microscopy, Data Analytics and Simulations

使用时间分辨电子显微镜、数据分析和模拟量化负载金属纳米颗粒的粗化动力学

• 批准号: 1809398
• 负责人: Eric Stach
• 金额: $ 53.26万
• 依托单位: University of Pennsylvania
• 依托单位国家: 美国
• 项目类别: Continuing Grant
• 财政年份: 2018
• 资助国家: 美国
• 起止时间: 2018-08-15 至 2022-07-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=1809398&HistoricalAwards=false
• 关键词: Quantifying; Coarsening; Kinetics; Supported; Metal

Non-Technical Abstract:Metallic nanoparticles find important applications in a variety of industries, most notably as catalysts in the chemical industry where they are used for the creation of fuels and related chemical byproducts. This is because their small size exposes many atoms on their surface: these surface atoms are the ones that help to improve their reactivity. However, their ability to function effectively for long periods is related to their ability to maintain this small size, even when being exposed to high temperatures and harsh environments that would normally lead to particle growth. This study will clarify the fundamental processes by which unwanted nanoparticle growth occurs by directly observing these processes using advanced microscopies, measuring the changes that occur in both individual particles and particle ensembles, and using computational modeling to clarify what processes are most responsible for particle growth. The studies will provide fundamental knowledge that can be used to increase the long-term performance of catalytic materials, leading to reduced energy cost and greater industrial yields. The project will include workforce preparation for the student involved via exposure to forefront materials characterization efforts, a deep interaction between experiment and theory, utilization of advanced data analytics approaches and visits to leading laboratories at IBM T.J. Watson Research Center and Brookhaven National Laboratory (BNL). The Summer Undergraduate Laboratory Internship (SULI) program and the Louis Stokes Alliances for Minority Participation (LS-AMP) at BNL will bring in students from the University of Puerto Rico, Rio Piedras to participate in data analytics code development, as well the development of software for microscope image analysis that will be disseminated to the broader community.Technical Abstract:A combination of advanced transmission electron microscopy methods will be used to investigate the role of surface stress and interparticle diffusional interactions in nanoparticle coarsening, to quantify the interplay between evaporation, coarsening and ripening in supported nanoparticles systems, and to investigate the effects of substrate modification and relative levels of nanoparticle oxidation and reduction on these phenomena. The work will exploit high-frame rate image acquisition and semi-automated data analysis routines to produce accurate quantitative data from images. This data will be used in a self-consistent fashion to both provide inputs to and corroborate outcomes from computational simulations. The resulting studies will allow, quantitative understanding of how nanoscale processes affect coarsening and ripening and will suggest strategies to mitigate these process in supported metallic nanostructure systems.This award reflects NSF's statutory mission and has been deemed worthy of support through evaluation using the Foundation's intellectual merit and broader impacts review criteria.

非技术摘要：金属纳米颗粒在各种行业中有着重要的应用，最值得注意的是作为化学工业中的催化剂，用于制造燃料和相关的化学副产品。这是因为它们的小尺寸暴露了表面上的许多原子：这些表面原子有助于提高它们的反应性。 然而，它们长时间有效发挥作用的能力与它们保持这种小尺寸的能力有关，即使在暴露于通常会导致颗粒生长的高温和恶劣环境中也是如此。这项研究将阐明不需要的纳米颗粒生长发生的基本过程，通过使用先进的显微镜直接观察这些过程，测量单个颗粒和颗粒集合中发生的变化，并使用计算建模来阐明什么过程是最负责颗粒生长。 这些研究将提供可用于提高催化材料长期性能的基础知识，从而降低能源成本并提高工业产量。 该项目将包括通过接触前沿材料表征工作，实验和理论之间的深入互动，利用先进的数据分析方法以及访问IBM TJ沃森研究中心和布鲁克海文国家实验室（BNL）的领先实验室，为学生进行劳动力准备。BNL的暑期本科生实验室实习（SULI）计划和路易斯·斯托克斯少数民族参与联盟（LS-AMP）将吸引来自里约彼德拉斯波多黎各大学的学生参与数据分析代码开发，以及将传播到更广泛社区的显微镜图像分析软件的开发。技术摘要：先进的透射电子显微镜方法的组合将用于研究纳米颗粒粗化中表面应力和颗粒间扩散相互作用的作用，以量化蒸发，粗化和成熟的支持纳米粒子系统，并研究这些现象的基板改性和纳米粒子的氧化和还原的相对水平的影响。该工作将利用高帧速率图像采集和半自动数据分析例程来从图像中生成准确的定量数据。这些数据将以自洽的方式用于为计算模拟提供输入和证实结果。由此产生的研究将允许，纳米尺度的过程如何影响粗化和成熟的定量理解，并将提出战略，以减轻这些过程中支持的金属纳米结构systems.This奖项反映了NSF的法定使命，并已被认为是值得通过评估使用基金会的智力价值和更广泛的影响审查标准的支持。

项目成果

Exploiting Automatic Image Processing and In-situ Transmission Electron Microscopy to Understand the Stability of Supported Nanoparticles

利用自动图像处理和原位透射电子显微镜来了解负载纳米颗粒的稳定性

• DOI: 10.1017/s1431927622011588
• 发表时间: 2022
• 期刊: Microscopy and Microanalysis
• 影响因子: 2.8
• 作者: Horwath, James P.;Vyas, Leena;Zakharov, Dmitri N.;Mégret, Rémi;Voorhees, Peter W.;Stach, Eric A.
• 通讯作者: Stach, Eric A.

Non-equilibrium Structural Phase Transformations in Atomically Thin Transition Metal Dichalcogenides

原子薄过渡金属二硫属化物中的非平衡结构相变

• DOI: 10.1017/s1431927620015342
• 发表时间: 2020
• 期刊: Microscopy and Microanalysis
• 影响因子: 2.8
• 作者: Kumar, Pawan;Horwath, James;Foucher, Alexandre;Price, Chrisopher;Acero, Natalia;Shenoy, Vivek;Jariwala, Deep;Stach, Eric;Alsem, Daan Hein
• 通讯作者: Alsem, Daan Hein

Operando Electrochemical TEM of Solid-State Energy Storage Materials Using a Probe-Based Biasing Holder

使用基于探针的偏压支架对固态储能材料进行操作电化学 TEM

• DOI: 10.1017/s1431927619011279
• 发表时间: 2019
• 期刊: Microscopy and Microanalysis
• 影响因子: 2.8
• 作者: Singh, Nikhilendra;Horwath, James;Foucher, Alexandre;Arthur, Timothy S.;Rodríguez Manzo, Julio A.;Alsem, Daan Hein;Stach, Eric
• 通讯作者: Stach, Eric

Using Operando Electrochemical TEM as Part of a Correlative Approach to Characterize Failure Modes in Solid-state Energy Storage Devices

使用 Operando 电化学 TEM 作为相关方法的一部分来表征固态储能器件的故障模式

• DOI: 10.1017/s1431927620018206
• 发表时间: 2020
• 期刊: Microscopy and Microanalysis
• 影响因子: 2.8
• 作者: Singh, Nikhilendra;Horwath, James;Arthur, Timothy;Alsem, Daan Hein;Stach, Eric
• 通讯作者: Stach, Eric

Understanding the Relationship Between Air Exposure, Electron Dose and Beam Damage in Solid Electrolyte Materails

了解固体电解质材料中空气暴露、电子剂量和束损伤之间的关系

• DOI: 10.1017/s143192762002423x
• 发表时间: 2020
• 期刊: Microscopy and Microanalysis
• 影响因子: 2.8
• 作者: Stach, Eric;Horwath, James;Singh, Nikhilendra;Arthur, Timothy;Alsem, Daan Hein;Salmon, Norman
• 通讯作者: Salmon, Norman