Collaborative Research: Micromechanics of Meniscus-bound Particle Clusters

合作研究：弯月面束缚粒子簇的微观力学

• 批准号: 2030537
• 负责人: Charles Schroeder
• 金额: $ 21.8万
• 依托单位: University of Illinois at Urbana-Champaign
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 2020
• 资助国家: 美国
• 起止时间: 2020-09-01 至 2024-08-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=2030537&HistoricalAwards=false
• 关键词: Collaborative; Research; Micromechanics; Meniscus; bound

Surface tension phenomena are important in a variety of physical processes including blending of immiscible fluids, formation of sprays and aerosols and foaming of plastics. This collaborative project concerns particle-liquid mixtures that are generally called particulate suspensions. Examples include slurries encountered in mineral and ceramics processing, particle-filled molten plastics, and printing inks. In such particulate suspensions, the addition of a second immiscible liquid induces particle "sticking" and aggregation due to surface tension and capillary forces. A familiar example is a sandcastle whose strength comes from small water droplets which bind the sand grains together by capillary forces. This project will conduct fundamental studies of interparticle capillary forces in mixing flows. Particle clusters bound by capillary forces will be placed in well-defined flows and studied using new methods in automated flow control. This work aims to understand the flow dynamics of particle clusters and the limits of their stability, which refers to the conditions under which clusters rupture due to the applied flow. Over the past decade, surface tension-induced particle clustering has been exploited for a wide range materials and materials-processing applications including macroporous ceramics, 3D printing, conductive plastics, and printing electronic circuits. The results of this project will enable rational design of mixing operations that exploit capillary forces to develop new materials.In multiphase suspensions containing particles and two immiscible liquids, capillary forces can induce particle clustering. The clusters comprise two or more particles bound by a meniscus liquid. In this project, the dynamics and rupture mechanics of particle clusters in simple shear or planar extensional flow fields will be studied using video microscopy and automated flow control. A feedback-controlled microfluidic device known as a Stokes trap will be used to precisely manipulate particles using viscous forces, to create well-defined meniscus-bound particle clusters, and to subject the clusters to precisely controlled flows. This work aims to achieve a fundamental understanding of the dynamics and rupture of particle clusters in well-defined flows. The project will reveal fundamentally new information, including the criteria for rupture of particle clusters, and how these criteria depend on the composition of the cluster, viscosity of the meniscus fluid, and particle roughness. Thedesign of mixing operations for liquid/liquid/particle mixtures is presently empirical in nature. This project will establish micromechanics-based design rules for such mixing operations that exploit capillary forces to develop new materials. The project will form the basis for training of graduate and undergraduate students. The two principal investigators will conduct numerous outreach activities at the undergraduate and pre-college level, including recruitment of underrepresented groups into their research groups, and mentorship of high-school students.This award reflects NSF's statutory mission and has been deemed worthy of support through evaluation using the Foundation's intellectual merit and broader impacts review criteria.

表面张力现象在各种物理过程中都很重要，包括不混相流体的混合、喷雾剂和气溶胶的形成以及塑料的发泡。这个合作项目涉及颗粒-液体混合物，通常被称为颗粒悬浮液。例如在矿物和陶瓷加工中遇到的浆料，填充颗粒的熔融塑料和印刷油墨。在这种颗粒悬浮液中，由于表面张力和毛细力的作用，加入第二种不混溶液体会导致颗粒“粘附”和聚集。一个熟悉的例子是沙堡，它的强度来自于小水滴，这些小水滴通过毛细管力将沙粒结合在一起。本项目将进行混合流中颗粒间毛细力的基础研究。受毛细力约束的颗粒团簇将被放置在定义良好的流动中，并使用自动化流动控制的新方法进行研究。这项工作旨在了解颗粒团簇的流动动力学及其稳定性的极限，这是指由于施加的流动而导致团簇破裂的条件。在过去的十年中，表面张力引起的颗粒聚类已被广泛用于材料和材料加工应用，包括大孔陶瓷、3D打印、导电塑料和印刷电子电路。该项目的结果将使合理设计利用毛细力开发新材料的混合操作成为可能。在含有颗粒和两种不混相液体的多相悬浮液中，毛细力可以诱导颗粒聚集。该簇由两个或多个由半月板液体结合的粒子组成。在本项目中，将使用视频显微镜和自动流动控制技术研究颗粒团簇在简单剪切或平面拉伸流场中的动力学和破裂力学。一种被称为斯托克斯陷阱的反馈控制微流体装置将用于利用粘性力精确地操纵颗粒，创建定义良好的半月板束缚颗粒簇，并使簇受到精确控制的流动。这项工作的目的是实现一个基本的理解动力学和破裂的粒子簇在明确定义的流动。该项目将揭示基本的新信息，包括颗粒簇破裂的标准，以及这些标准如何依赖于簇的组成、半月板流体的粘度和颗粒粗糙度。目前液体/液体/颗粒混合物的混合操作设计本质上是经验的。该项目将建立基于微力学的设计规则，利用毛细管力开发新材料的混合操作。该项目将成为培养研究生和本科生的基础。两位主要研究人员将在本科和大学预科阶段开展大量的外展活动，包括招募代表性不足的群体加入他们的研究小组，以及指导高中生。该奖项反映了美国国家科学基金会的法定使命，并通过使用基金会的知识价值和更广泛的影响审查标准进行评估，被认为值得支持。

项目成果

Understanding How Coacervates Drive Reversible Small Molecule Reactions to Promote Molecular Complexity

• DOI: 10.1021/acs.langmuir.1c02231
• 发表时间: 2021-12-14
• 期刊: LANGMUIR
• 影响因子: 3.9
• 作者: Jacobs, Michael, I;Jira, Edward R.;Schroeder, Charles M.
• 通讯作者: Schroeder, Charles M.

3D manipulation and dynamics of soft materials in 3D flows

3D 流动中软材料的 3D 操纵和动力学

• DOI: 10.1122/8.0000600
• 发表时间: 2023
• 期刊: Journal of Rheology
• 影响因子: 3.3
• 作者: Tu, Michael Q.;Nguyen, Hung V.;Foley, Elliel;Jacobs, Michael I.;Schroeder, Charles M.
• 通讯作者: Schroeder, Charles M.