MRI: Acquisition of a Single Crystal X-ray Diffractometer
MRI:获取单晶 X 射线衍射仪
基本信息
- 批准号:2117040
- 负责人:
- 金额:$ 35.49万
- 依托单位:
- 依托单位国家:美国
- 项目类别:Standard Grant
- 财政年份:2021
- 资助国家:美国
- 起止时间:2021-08-01 至 2024-07-31
- 项目状态:已结题
- 来源:
- 关键词:
项目摘要
This award to California State University-Long Beach is supported by the Major Research Instrumentation and the Chemistry Research Instrumentation programs to support and improve research by professor Xianhui Bu from and colleagues Michael Schramm, Young-Seok Shon and Fangyuan Tian. The institution is acquiring a single crystal X-ray difffractometer (SCXRD). In general, an X-ray diffractometer allows accurate and precise measurements of the full three-dimensional structure of a molecule, including bond distances and angles, and provides accurate information about the spatial arrangement of a molecule relative to neighboring molecules. The studies described here impact many areas, including organic and inorganic chemistry, materials chemistry, geology and biochemistry. This instrument is an integral part of teaching as well as research and research training of undergraduate students in chemistry and biochemistry at this Hispanic Serving Institution as well as California State University Los Angeles. The instrumentation provides direct research experience for students in a variety of courses distributed in various departments and other neighboring universities. The award of the X-ray diffractometer is aimed at enhancing research and education at all levels. The science enabled by this instrument provides relevant societal benefits through the development of new materials to address energy production, new catalysts to improve the synthesis of commodity and industrial chemicals. The instrumentation is also used for studying amino-acid-based homochiral porous materials with zeolite-type frameworks and for developing acid-base stable metal-organic framework materials (MOFs). In addition, it benefits the exploration of mono and bisgold resorcinarenes as supramolecular catalysts and for investigating mechanisms of MOF catalysis based on structures of MOFs and trapped reaction intermediates (in collaboration with California State University Los Angeles). The diffractometer is also used to characterize fluorescent metal-organic frameworks for sensing explosive compounds. Additionally, the diffractometer is utilized for the structural characterization of non-heme iron nitrosyl complexes and catalysis made from monometallic palladium, platinum and iridium nanoclusters.This award reflects NSF's statutory mission and has been deemed worthy of support through evaluation using the Foundation's intellectual merit and broader impacts review criteria.
这个奖项给加州州立大学长滩分校海滩是由主要研究仪器和化学研究仪器计划的支持,以支持和改善由教授Xianhui Bu和同事Michael Schramm,Young-Seok Shon和Fangyuan Tian的研究。该机构正在购置一台单晶X射线衍射仪(SCXRD)。一般来说,X射线衍射仪允许准确和精确地测量分子的完整三维结构,包括键距和角度,并提供关于分子相对于相邻分子的空间排列的准确信息。这里描述的研究影响了许多领域,包括有机和无机化学,材料化学,地质学和生物化学。该仪器是教学的一个组成部分,以及研究和本科生在化学和生物化学在这个西班牙裔服务机构以及加州州立大学洛杉矶的研究培训。该仪器为学生提供了直接的研究经验,分布在各个部门和其他邻近大学的各种课程。颁发X射线衍射仪的目的是加强各级的研究和教育。该工具所支持的科学通过开发新材料来解决能源生产问题,开发新催化剂来改善商品和工业化学品的合成,从而提供相关的社会效益。该仪器还用于研究具有沸石型骨架的基于氨基酸的纯手性多孔材料和开发酸碱稳定的金属有机骨架材料(MOF)。此外,它有利于单和双金间苯二酚芳烃作为超分子催化剂的探索,并用于基于MOF和捕获的反应中间体的结构研究MOF催化机制(与加州州立大学洛杉矶合作)。该衍射仪还用于表征用于感测爆炸性化合物的荧光金属有机框架。此外,该衍射仪还可用于非血红素铁亚硝酰络合物的结构表征,以及由钼钯、铂和铱纳米团簇制成的催化剂。该奖项反映了NSF的法定使命,并通过使用基金会的知识价值和更广泛的影响审查标准进行评估,被认为值得支持。
项目成果
期刊论文数量(1)
专著数量(0)
科研奖励数量(0)
会议论文数量(0)
专利数量(0)
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Xianhui Bu其他文献
Design und Synthese von Materialien mit offenen Gerüsten: ein unterbrochener und ein aufgeweiteter Sodalith
材料的设计和合成:ein unterbrochener und ein aufgeweiiteter Sodalith
- DOI:
10.1002/ange.19951071627 - 发表时间:
1995 - 期刊:
- 影响因子:0
- 作者:
Ping Feng;Xianhui Bu;G. D. Stucky - 通讯作者:
G. D. Stucky
Induction of chiral porous solids containing only achiral building blocks
仅含非手性结构单元的手性多孔固体的诱导
- DOI:
10.1038/nchem.628 - 发表时间:
2010-04-23 - 期刊:
- 影响因子:20.200
- 作者:
Russell E. Morris;Xianhui Bu - 通讯作者:
Xianhui Bu
刚性硫族分子筛通过逐步离子交换策略实现放射性铯离子高效快速去除
- DOI:
- 发表时间:
2016 - 期刊:
- 影响因子:8.6
- 作者:
Shuao Wang;Xianhui Bu;Pingyun Feng;Tao Wu - 通讯作者:
Tao Wu
Efficient Gas-Sensing for Formaldehyde with 3D Hierarchical Co3O4 Derived from Co5‑Based MOF Microcrystals
利用 Co5 基 MOF 微晶衍生的 3D 分级 Co3O4 对甲醛进行高效气敏
- DOI:
- 发表时间:
2017 - 期刊:
- 影响因子:0
- 作者:
Wei Zhou;Ya-Pan Wu;Jun Zhao;Wen-Wen Dong;Xiu-Qing Qiao;Dong-Fang Hou;Xianhui Bu;Dong-Sheng Li - 通讯作者:
Dong-Sheng Li
Metal–organic frameworks with two different-sized aromatic ring-confined nanotraps for benchmark natural gas upgrade
具有两种不同尺寸芳香环限制纳米陷阱的金属有机框架用于基准天然气升级
- DOI:
10.1039/d4sc04387a - 发表时间:
2024-10-03 - 期刊:
- 影响因子:7.400
- 作者:
Shu-Yi Li;Ying-Ying Xue;Jia-Wen Wang;Hai-Peng Li;Jiao Lei;Hong-Juan Lv;Xianhui Bu;Peng Zhang;Ying Wang;Wen-Yu Yuan;Quan-Guo Zhai - 通讯作者:
Quan-Guo Zhai
Xianhui Bu的其他文献
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{{ truncateString('Xianhui Bu', 18)}}的其他基金
RUI: New Ultrastable Crystalline Porous Materials
RUI:新型超稳定结晶多孔材料
- 批准号:
2105961 - 财政年份:2021
- 资助金额:
$ 35.49万 - 项目类别:
Standard Grant
RUI: Development of A Synthetic Platform for Highly Tunable Cationic Porous Materials
RUI:开发高度可调的阳离子多孔材料的合成平台
- 批准号:
1708850 - 财政年份:2017
- 资助金额:
$ 35.49万 - 项目类别:
Standard Grant
Homochiral Crystalline Porous Materials for Enantioselective Applications
用于对映选择性应用的同手性结晶多孔材料
- 批准号:
1309347 - 财政年份:2014
- 资助金额:
$ 35.49万 - 项目类别:
Continuing Grant
CAREER: Synthesis, Structures, and Properties of Crystalline Boron-Based Porous Materials
职业:结晶硼基多孔材料的合成、结构和性能
- 批准号:
0846958 - 财政年份:2009
- 资助金额:
$ 35.49万 - 项目类别:
Continuing Grant
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