Mass transfer of rising gas bubbles in reacting liquids

这个项目的思想是研究气泡相互作用对反应性气泡流传质的影响。在此之前，实验工作主要集中在确定流体力学、传质和化学反应之间的相互作用。由于在实际应用中多个气泡相互作用，这里将研究不同类型气泡地层中的某些气泡。在第一个资助期开发的实验系统将进一步用于补充单泡实验。这些实验为评价相互作用气泡形成的结果提供了必要的基础信息。互补单泡研究的目的是确定传质系数。这些是根据气泡与（反应）液相接触时气泡大小的变化来确定的。实验在两个设备上进行，这两个设备在第一个资助期得到了进一步的发展。该装置为气泡上升通道和逆流池。变化的参数有：化学体系（WG kl<s:1> fers/Schindler/Herres-Pawlis）、气泡大小、气泡与液体接触时间、压力、温度、液相中萃取物浓度。结果将用调整后的或新的Sherwood相关性进行数学建模，同时合理地纳入所有影响参数。这些相关性将用于比较气泡附近具有更复杂的速度和浓度场的系统。这些字段将在受控条件下创建。将测试几种方法。将研究气泡链、气泡阵列和气泡群，这些气泡将被单个气泡跟随而停止。为了进行比较，优先项目的其他小组在第一个资助期内开发和研究的湍流促进剂也将进行测试（WG Kähler/ schl<e:1> ter/Thoeming）。除了研究在第一个资助期内发展的化学系统外，还将研究新的和进一步发展的具有平行和/或连续化学反应的系统。在某些情况下，这需要在实验中采用新的方法来进行精确的量化。全自动实验设备将配备新的固定和移动光谱测量技术（WG Rinke/Simon）。这种方法有很大的潜力，因为化学反应的发展有竞争的化学反应，导致不同的变色。选择的方法是在气泡上升过程中使用光学测量技术跟踪气泡，提供了在不同控制条件下上升路径、气泡形状和收缩行为的结果。这个信息对于数字工作组来说是非常有趣的，因为它可以很容易地用于验证（WG Bothe/Rzehak/Sommerfeld）。

The idea of this project is the investigation of the influence of the interaction of bubbles on the mass transfer in reactive bubbly flows. Previously, the experimental work was focused on the determination of the interaction between fluid dynamics, mass transfer and chemical reaction. As in practical applications multiple bubbles interact, here certain bubbles in different types of bubble formations will be investigated. The experimental systems developed in the first funding period will further be used for complementary single bubble experiments. These experiments provide the necessary basic information to evaluate the results of interacting bubble formations.The aim of the complementary single bubble investigations is the determination of mass transfer coefficients. These are determined based on the change of the bubble size during the bubble's contact with the (reacting) liquid phase. The experiments are performed in two apparatuses which were further developed in the first funding period. The apparatuses are a bubble ascent channel and a counter current flow cell.Varied parameters are: The chemical system (WG Klüfers/Schindler/Herres-Pawlis), bubble size, contact time between bubble and liquid, pressure, temperature, educt concentration in the liquid phase.The results will be mathematically modeled with adjusted or new Sherwood correlations while reasonably incorporating all influencing parameters. These correlations will be used to compare systems with more complex velocity and concentration fields in the vicinity of the bubble. These fields will be created under controlled conditions. Several approaches will be tested. A chain of bubbles, an array of bubbles and a bubble swarm which will be stopped with a single bubble following will be investigated. For comparison, turbulence promoters which were developed and investigated in the first funding period by other groups in the priority program will be tested as well (WG Kähler/Schlüter/Thoeming). Besides the investigation of the chemical systems de-veloped in the first funding period, the new and further developed systems with parallel and/or consecutive chemical reactions will be investigated. In some cases, this requires new ap-proaches in the experiments to be able do an accurate quantification. The fully automated ex-perimental apparatuses will be equipped with new stationary and moving spectral measurement techniques (WG Rinke/Simon). This approach has great potential as chemical reactions are developed which have competing chemical reactions resulting in differing discolorations.The chosen approach of following the bubble during its ascent with an optical measurement technique provides results of the rising path, bubble shape and shrinkage behavior under diverse controlled conditions. This information is of high interest for numerically working groups as it can easily be used for validation (WG Bothe/Rzehak/Sommerfeld).