Selective hydrogenation of arenes and heteroarenes by manganese-based catalysts

锰基催化剂芳烃和杂芳烃的选择性加氢

• 批准号: 447724917
• 负责人: Professor Dr. Matthias Beller
• 金额: --
• 依托单位: Leibniz-Institut für Katalyse e. V. an der Universität Rostock (LIKAT)
• 依托单位国家: 德国
• 项目类别: Research Grants
• 资助国家: 德国
• 项目状态: 未结题
• 来源: https://gepris.dfg.de/gepris/projekt/447724917?language=en
• 关键词: Selective; hydrogenation; arenes; heteroarenes; manganese

Within the scope of this project manganese catalysts for the hydrogenation of aromatics and heteroaromatics are to be developed for the first time. Based on the well-defined synthesis of Mn-based coordination polymers and manganese-containing MOF's, new supported Mn nanoparticles and Mn-Single Atom Catalysts (SAC's) will be produced and characterized (WP1). These materials are used in work package 2 (WP2) for the hydrogenation of aromatics and heteroaromatics. After optimization of the model systems and mechanistic studies (WP3), a number of synthetically interesting applications are planned (WP4). As interesting examples, the development of diastereoselective hydrogenations (e.g. thymol) and chemoselective processes using multiple aromatic compounds will be mentioned here.

在本项目范围内，首次开发用于芳烃和杂芳烃加氢的锰催化剂。基于Mn基配位聚合物和含锰MOF的明确合成，将生产和表征新的负载型Mn纳米颗粒和Mn单原子催化剂（SAC）（WP 1）。这些材料用于工作包2（WP 2）中，用于芳烃和杂芳烃的氢化。在优化模型系统和机理研究（WP 3）之后，计划了一些综合性的有趣应用（WP 4）。作为有趣的例子，非对映选择性氢化（如百里酚）和使用多种芳香族化合物的化学选择性方法的发展将在这里提到。