Catalysis of Reactive Organometallics

为了开发新的催化过程，已经制备了各种有机过渡金属配合物作为催化活性物种的模型，并且已经研究了它们与催化反应中的基元过程相关的性质。(1)各种新的有机钯和钌配合物的中性和阳离子性质已被制备和它们对烯烃，一氧化碳，亚胺，和异腈的反应性已被检查。(2)制备了新型旋光螺旋状聚合物，并对其液晶行为进行了研究。(3)作为钌催化Michael型C-C键形成催化作用的模型，本文合成了新型有机钌配合物，并对其性质进行了研究。(4)合成了新的含二茂铁基的有机铂配合物。(5)一氧化碳与丙烯共聚制备全同立构聚酮的新工艺已被发现。(6)实现了一种钯催化炔基酯与有机锌化合物结合转化为不饱和醇的新方法。

For developing novel catalytic processes various organotransition metal complexes have been prepared as models of catalytically active species and their properties relevant to elementary processes in catalytic reactions have been studied. (1) Various new organopalladium and ruthenium complexes of neutral and cationic nature have been prepared and their reactivities toward olefins, carbon monoxide, imines, and isocyanides have been examined. (2) Novel types of optically active, spiral-like polymers have been prepared and their properties showing the liquid crystal behavior have been examined. (3) As a model of ruthenium-catalyzed Michael type C-C bond forming catalysis new organoruthenium complexes have been prepared and their properties have been studied. (4) New organoplatinum complexes having ferrocenyl ligands have been synthesized. (5) Novel process of copolymerizing carbon monoxide and propylene to give isotactic polyketones has been discovered. (6) A new palladium-catalyzed process for converting alkynyl esters into unsaturated alcohols in combination with organozinc compounds has been realized.