Microchemistry Based on Single Colloidal and Aerosol Particles

基于单一胶体和气溶胶颗粒的微化学

• 批准号: 23245015
• 负责人: KITAMURA Noboru
• 金额: $ 32.2万
• 依托单位: Hokkaido University
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for Scientific Research (A)
• 财政年份: 2011
• 资助国家: 日本
• 起止时间: 2011-04-01 至 2014-03-31
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/en/grant/KAKENHI-PROJECT-23245015/
• 关键词: レーザー捕捉; 単一微粒子; コロイド; エアロゾル; マイクロ分析化学; コロイド粒子; レーザー捕捉・顕微分光; 機器分析; 顕微計測; エアロゾル液滴; コロイド液滴; ドナン膜電位

Novel techniques based on laser trapping - microspectroscopy on single micrometer-sized colloidal particles in solution as well as single aerosol water droplets in air have been developed. In particular, we have developed temperature- and moisture-controlled laser trapping of single aerosol water droplets in air. We also confirmed experimentally photoinduced aerosol droplet formation in air and its mechanistic aspects were elucidated. Furthermore, we succeeeded in determining the sizes of single aerosol droplets in a nanometer level based on whipering gallery mode resonances of Raman scattering light in single aerosol droplets. We also showed that the intraparticle diffusion of a cation dye in single cation-exchange resin microparticles was determined by the Donnan electric membrane potential generated at the resin/water interface, which was the first observation for single ion-exchange microparticles.

发展了一种基于激光捕获-显微光谱的溶液中单个微米级胶体颗粒和空气中单个气溶胶水滴的新技术。特别是，我们已经开发了温度和湿度控制的激光捕获空气中的单个气溶胶水滴。我们还证实了实验光诱导气溶胶液滴在空气中的形成和其机制方面进行了阐述。此外，我们成功地确定了单个气溶胶液滴的尺寸在纳米级的基础上的拉曼散射光的鞭梢画廊模式共振的单个气溶胶液滴。我们还表明，在单一的阳离子交换树脂微粒的阳离子染料的颗粒内扩散确定由在树脂/水界面，这是第一次观察到的单离子交换微粒产生的唐南电动膜电位。

项目成果

Dynamic Emission Quenching of a Novel Ruthenium(II) Complex by Carbon Dioxide in Solution

溶液中二氧化碳对新型钌(II)配合物的动态发射猝灭

• 发表时间: 2012
• 期刊: RSC Advances
• 影响因子: 3.9
• 作者: N. M. Cuong;S. Ishizaka;N. Kitamura;E. Sakuda
• 通讯作者: E. Sakuda

A Laser Trapping and Spectroscopy of Single Supercooled Water Droplets in Air

空气中单个过冷水滴的激光捕获和光谱分析

• 发表时间: 2011
• 作者: Abul K.Mallik;Kaori Shingo;Aika Ezaki;Tsuyoshi Sawada;Makoto Takafuji;Hirotaka Ihara;Shoji Ishizaka
• 通讯作者: Shoji Ishizaka

Laser Trapping-Microspectroscopy of Single Aerosol Droplets in Air

空气中单个气溶胶液滴的激光捕获显微光谱

• 发表时间: 2011
• 作者: Jian Zhao;Naoki Asao;Yoshinori Yamamoto;Tienan Jin;N. Kitamura
• 通讯作者: N. Kitamura

Spectroscopic Study on the Photoinduced Decarboxylation Mechanisms of Synthetic Pyrethroids

合成拟除虫菊酯光致脱羧机理的光谱研究

• 发表时间: 2012
• 期刊: Photochemical and Photobiological Sciences
• 影响因子: 3.1
• 作者: J. T. Lau;K. Hirsch;V. Zamudio-Bayer;A. Langenberg;M. Niemeyer;M. Kossick;B. Langbehn;A. Terasaki;T. Moller;and B. von Issendorff;Y. Suzuki
• 通讯作者: Y. Suzuki

In Situ Quantification of Ammonium Sulfate in Single Aerosol Droplets by Means of Laser Trapping and Raman Spectroscopy

通过激光捕获和拉曼光谱对单个气溶胶液滴中的硫酸铵进行原位定量

• 发表时间: 2013
• 期刊: Analytical Sciences
• 影响因子: 1.6
• 作者: S. Ishizaka;K. Yamauchi;and N. Kitamura
• 通讯作者: and N. Kitamura