The Studies on the Transition States in Chemical Reactions by Means of Spectroscopy and Dynamical Method

化学反应过渡态的光谱学和动力学方法研究

• 批准号: 60303001
• 负责人: SATO Shin
• 金额: $ 5.7万
• 依托单位: Tokyo Institute of Technology
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for Co-operative Research (A)
• 财政年份: 1985
• 资助国家: 日本
• 起止时间: 1985 至 1987
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-60303001/
• 关键词: Elementary chemical process; 遷移状態; 交叉分子線法; クラスター; トンネル効果; 分子交差法; マイクロ波分光; ファンデルワールス分子; レーザ誘起蛍光; TESICO法; ウィグナーの閾値則

This research group has been organized for the exchnge of the informations between most active researchers working in the field of elementary chemical processes.One of the most exciting problems in this field at present is how to get an insight into the transition state in chemical reaction. Since each member in this group has their own techniques and methods, the coordinater made opportunities to get together and let them to discuss the problems they were encountering with. As the consequence, many problems have been solved and a lot of suggestions were obtained. Some of the results have been published in the report to the Ministry of Education, Science and Culture. This report will become a mile-stone in the study of elementary chemical processes in our country.

这个研究小组是为在基本化学过程领域工作的最活跃的研究人员之间的信息交流而组织的，目前该领域最令人兴奋的问题之一是如何深入了解化学反应中的过渡态。由于每个人都有自己的技巧和方法，协调员创造机会让他们聚在一起，讨论他们遇到的问题。在此基础上，提出了一些建议，解决了一些问题.部分结果已在提交教育、科学和文化部的报告中公布。该报告将成为我国基础化学过程研究的里程碑。

项目成果

K. Fuke, S. Nonose, N. Kikuchi, K. Kaya: "Reaction of Aluminum Clusters with Oxygen and Ammonia" J. Phys. Chem.in press.

K. Fuke、S. Nonose、N. Kikuchi、K. Kaya：“铝簇与氧气和氨的反应”J. Phys。

M. Kamachi, K. Kuwata, T.Sumiyoshi, W. Schnabel: "ESR Studies on Photo-dissciation of 2,4,6-Trimethylbenzoyl Phosphine Oxide" J. Chem. Soc., Perkin Trans.,. in press.

M. Kamachi、K. Kuwata、T.Sumiyoshi、W. Schnabel：“2,4,6-三甲基苯甲酰基氧化膦的光解 ESR 研究”J. Chem。

T. Kobayashi, M. Futakami, O. Kajimoto: "Charge-transfer State of 4-Dimethylamino-3,5-diethylbenzonitrile Studied ina Free Jet" Chem. Phys. Letters. in press.

T. Kobayashi、M. Futakami、O. Kajimoto：“在自由射流中研究的 4-二甲氨基-3,5-二乙基苯甲腈的电荷转移状态” Chem。

M. Tsuji, K. Mizukami, H. Obase, Y. Nishimura: "Elwctronic Excitation of the d^3 _i and a'^3 ^+ states of Carbon Monoxide by Metastable Kr(^3p_2) Atoms" Chem. Phys. Letters. 143. 483 (1988)

M. Tsuji、K. Mizukami、H. Obase、Y. Nishimura：“亚稳态 Kr(^3p_2) 原子对一氧化碳 d^3 _i 和 a^3 ^ 状态的电子激发” Chem。

S. Nagaoka, S. Suzuki, I. Koyano: "Investigation of Fragmentation Processes Following Core Photoionization of Organometallic Molecules in the Vapor Phase" Nucl. Instr. Meth.in press.

S. Nagaoka、S. Suzuki、I. Koyano：“气相有机金属分子核心光离子化后的碎裂过程的研究”Nucl。