Development of a novel method for preparing functional films by two-liquid-phase interface electrodeposition

一种两液相界面电沉积制备功能薄膜的新方法的开发

• 批准号: 08555167
• 负责人: KANEKO Hiroyuki
• 金额: $ 0.51万
• 依托单位: Akita University
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for Scientific Research (B)
• 财政年份: 1996
• 资助国家: 日本
• 起止时间: 1996 至 1997
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-08555167/
• 关键词: metallic films; organic films; interfacial phenomenon; electrodeposition; electrooxidation; gold; zinc; polypyrrole; 有機液体

It is known that the electrolysis at the interface between an aqueous solution containing metallic ions and an immiscible organic liquid results in the growth of leaf-like deposits along the interface. We found recently film growth of metals, such as zinc, cobalt, etc.in the certain experimental conditions. Therefore, as an application of this method, it will be expected to prepare new funcrional films.From this point of view, the purpose of this research project is to develop this method and to challenge to new preparations of metallic and organic films, in order to establish the two-liquid-phase interface electrodeposition method as a preparation method of functional films. In 1996 fiscal year, we investigated several factors governing the preparation of metallic films by cathodic reduction, and succeeded in preparation of gold films. In 1997 fiscal year, we tried to prepare conducting organic films by anodic oxidation, and succeeded in preparation of polypyrrole films. And also, we made computer-controlled apparatus to perform continuous growth of filmy deposits. From these results, it is confirmed that this method is to be a promising noble method to obtain continuously filmy conductint materials.

众所周知，含有金属离子的水溶液和不混溶的有机液体之间的界面上的电解会导致沿界面的叶状沉积物的生长。在某些实验条件下，我们发现金属的胶片生长，例如锌，钴等。因此，作为这种方法的应用，预计将准备新的插曲电影。从这种观点来看，该研究项目的目的是开发这种方法，并挑战金属和有机膜的新制剂，以建立两种液体相位界面界面的电界方法作为功能膜的准备方法。在1996财政年度，我们调查了通过减少阴极制备金属膜的几个因素，并成功地制备了黄金膜。在1997财政年度，我们试图通过阳极氧化制备进行有机膜，并成功地制备了多吡咯膜。而且，我们制作了计算机控制的设备，以执行膜沉积物的持续生长。从这些结果中可以证实，这种方法是一种有前途的贵族方法，以获取连续的胶片电导材料。

项目成果

Toshiaki Mitsui: "A novel preparation of gold films by electrodeposition at the interface between two liquid phases" Journal of Applied Electrochemistry. 27. (1997)

Toshiaki Mitsui：“通过在两个液相之间的界面上电沉积来制备金膜的新方法”《应用电化学杂志》。

T.Mitsui and H.Kaneko: "A novel preparation of gold films by electrodeposition at the interface between a Na(AuCl_4)-CuSO_4 aqueous phase and an immiscible organic phase" Journal of Applied Electrochemistry. 27・9. 1100-1105 (1997)

T.Mitsui 和 H.Kaneko：“通过在 Na(AuCl_4)-CuSO_4 水相和不混溶有机相之间的界面电沉积制备金膜”，应用电化学杂志 27・9（1997 年）。 ）

T.Mitsui and H.Kaneko: "A novel preparation of gold films by electrodeposition at the interface between a Na(AhCl_4)-CuSo_4 agulous phasl and an immisable organic bhase" Journal of Applied Electrochemistry. 27・9. 1100-1105 (1997)

T.Mitsui 和 H.Kaneko：“通过在 Na(AhCl_4)-CuSo_4 凝集相和不可混溶有机相之间的界面电沉积制备金膜”，应用电化学杂志 27・9（1997 年）。 ）

T.Mitsui and H.Kaneko: "A novel preparation of gold films by electrodeposition at the interface between a Na (AuCl_4)-CuSO_4 aqueous phase and an immiscible organic phases" J.Appl.Electrochem.27-9. 1100-1105 (1997)

T.Mitsui 和 H.Kaneko：“通过在 Na (AuCl_4)-CuSO_4 水相和不混溶有机相之间的界面电沉积制备金膜的新方法”J.Appl.Electrochem.27-9。