Preparation of Metallic Films at the Interface between Two Liquid Phases
两液相界面金属膜的制备
基本信息
- 批准号:03805059
- 负责人:
- 金额:$ 0.9万
- 依托单位:
- 依托单位国家:日本
- 项目类别:Grant-in-Aid for General Scientific Research (C)
- 财政年份:1991
- 资助国家:日本
- 起止时间:1991 至 1993
- 项目状态:已结题
- 来源:
- 关键词:
项目摘要
Two-dimentional metal deposits can be obtained by the cathodic reduction of metal ions at an interface between an organic liquid and an aqueous solution of the metal salt under appropriate experimental conditions. The effect of metallic species and its concentration, organic liquid, temperature, applied voltage and current on the morphology of the deposit was studied in detail. As a result, filmy deposits of zinc, cobalt, copper, silver and gold were obtained ; filmy growth was favored at the interface with an organic liquid having high interfacial tension, at high temperatures than room temperature and at relatively low applied voltages.We then tried to continuously prepare metallic films as an application of above phenomenon. The cathode was an aluminum foil floating at the interface, one end of which was connected to the rotating drum. The anode was positioned vertically to the cathode. A film growing along the interface was continuously rolled onto the drum by a computer-controlled stepping motor. The principal advantage of this technique are as follows : metallic films are easily obtainable without using any substate for deposition, and the crystal direction of the film can be controlled.
在适当的实验条件下,通过在有机液体和金属盐水溶液之间的界面上阴极还原金属离子,可以获得二维金属沉积。详细研究了金属种类及其浓度、有机液体、温度、外加电压和电流对镀层形貌的影响。结果得到了锌、钴、铜、银和金的薄膜沉积,在界面张力较高、温度高于室温、外加电压较低的有机液体的界面上有利于薄膜的生长。阴极是漂浮在界面上的铝箔,其一端连接到旋转滚筒上。阳极与阴极垂直放置。计算机控制的步进电机将沿界面生长的薄膜连续滚动到鼓上。这种技术的主要优点是:无需使用任何衬底即可获得金属薄膜,并且薄膜的晶体方向可控。
项目成果
期刊论文数量(32)
专著数量(0)
科研奖励数量(0)
会议论文数量(0)
专利数量(0)
Hiroyuki Kaneko,Hitoshi Taimatsu,Tsukasa Takahashi: "Preparation of Cobalt Films by Electrodeposition at the Interface between Two Liquid Phases" Denki Kagaku. 61. 827-829 (1993)
Hiroyuki Kaneko、Hitoshi Taimatsu、Tsukasa Takahashi:“通过在两液相界面上电沉积制备钴薄膜”电气化学。
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金児紘征 泰松斉 阪原久: "金属塩水溶液/有機液体界面で成長した各種金属葉の形態" 秋田大学鉱山学部資源地学研究施設報告. 56. 187-191 (1991)
Hiroyuki Kaneko、Hitoshi Yasumatsu 和 Hisashi Sakahara:“在金属盐水溶液/有机液体界面生长的各种金属叶子的形态”秋田大学矿业学院资源地质研究所的报告 56. 187-191(1991 年)。 )
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Hiroyuki Kaneko, Hitoshi Taimatsu and Hisashi Sakahara: "Preparation of Metallic Films by Electrodeposition at the Interface between Two Liquid Phases" Materials Transaction, JIM. 34. 732-734 (1993)
Hiroyuki Kaneko、Hitoshi Taimatsu 和 Hisashi Sakahara:“通过在两液相界面上的电沉积制备金属薄膜”Materials Transaction,JIM。
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Hiroyuki Kaneko, Hisashi Sakahara and Hitoshi Taimatsu: "Filmy Growth of Metal Leaves Electrodeposited at the Metallic Salt Solution / Organic Liquid Interface (in Japanese)" J.Mining and Materials Processing of Japan. 107. 542-546 (1991)
Hiroyuki Kaneko、Hisashi Sakahara 和 Hitoshi Taimatsu:“在金属盐溶液/有机液体界面电沉积金属叶的薄膜生长(日语)”J.Mining and Materials Manufacturing of Japan。
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阪原 久・金児 紘征,泰松 斉: "酢酸エステル/硫酸亜鉛水溶液界面に電析した亜鉛葉の形態" 表面技術. 43. 1059-1064 (1992)
Hisashi Sakahara、Hiroyuki Kaneko 和 Hitoshi Yasumatsu:“沉积在醋酸盐/硫酸锌水溶液界面的锌叶的形态”表面技术 43. 1059-1064 (1992)。
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KANEKO Hiroyuki其他文献
みちのくの仏像と東北における仏像表現の受容
陆奥的佛像与东北地区佛像表现的接受
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- 发表时间:
2015 - 期刊:
- 影响因子:0
- 作者:
ABE Hisashi ;WATANABE Ken;ISHIKAWA Atsuko;NOSHIRO Shuichi;FUJII Tomoyuki;IWASA Mitsuharu;KANEKO Hiroyuki;WADA Hiroshi;山盛弥生;宮下 修一;村田雄二郎;Tatsuya Higaki;笠原一人;牧山康志;山盛弥生;山根聡;西木政統;笠原一人;石井剛;太田佳鈴;松村耕光;Mikio Nakahara;加藤尚武;平子友長;丸山士郎 - 通讯作者:
丸山士郎
National Wealth without military strength?: The Four Postwar Eras in Modern East Asia
国家财富没有军事实力?
- DOI:
- 发表时间:
2015 - 期刊:
- 影响因子:0
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ABE Hisashi ;WATANABE Ken;ISHIKAWA Atsuko;NOSHIRO Shuichi;FUJII Tomoyuki;IWASA Mitsuharu;KANEKO Hiroyuki;WADA Hiroshi;山盛弥生;宮下 修一;村田雄二郎 - 通讯作者:
村田雄二郎
蘭渓道隆の頂相―建仁寺西来院調査報告を中心に
兰溪道流的巅峰:以建仁寺西雷院调查报告为中心
- DOI:
- 发表时间:
2014 - 期刊:
- 影响因子:0
- 作者:
ABE Hisashi ;WATANABE Ken;ISHIKAWA Atsuko;NOSHIRO Shuichi;FUJII Tomoyuki;IWASA Mitsuharu;KANEKO Hiroyuki;WADA Hiroshi;山盛弥生;宮下 修一;村田雄二郎;Tatsuya Higaki;笠原一人;牧山康志;山盛弥生;山根聡;西木政統;笠原一人;石井剛;太田佳鈴;松村耕光;Mikio Nakahara;加藤尚武;平子友長;丸山士郎;太田佳鈴;平子友長;TONAGA Yasushi;郡司ペギオ幸夫;浅見龍介 - 通讯作者:
浅見龍介
Non-destructive method for species identification of historical wooden artifacts using NIR spectroscopy: separation of softw
使用近红外光谱法对历史木制文物进行物种鉴定的无损方法:软件分离
- DOI:
- 发表时间:
2015 - 期刊:
- 影响因子:0
- 作者:
ABE Hisashi ;WATANABE Ken;ISHIKAWA Atsuko;NOSHIRO Shuichi;FUJII Tomoyuki;IWASA Mitsuharu;KANEKO Hiroyuki;WADA Hiroshi - 通讯作者:
WADA Hiroshi
(河辺青蘭筆)折枝富貴図扇面
(川边青兰)折田富纪扇面
- DOI:
- 发表时间:
2014 - 期刊:
- 影响因子:0
- 作者:
ABE Hisashi ;WATANABE Ken;ISHIKAWA Atsuko;NOSHIRO Shuichi;FUJII Tomoyuki;IWASA Mitsuharu;KANEKO Hiroyuki;WADA Hiroshi;山盛弥生;宮下 修一;村田雄二郎;Tatsuya Higaki;笠原一人;牧山康志;山盛弥生 - 通讯作者:
山盛弥生
KANEKO Hiroyuki的其他文献
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{{ truncateString('KANEKO Hiroyuki', 18)}}的其他基金
Production of porcine blastocysts using sperm and oocytes retrieved from immature gonadal tissues grafted into nude mice
利用从未成熟性腺组织中取出的精子和卵母细胞移植到裸鼠体内产生猪囊胚
- 批准号:
17K19333 - 财政年份:2017
- 资助金额:
$ 0.9万 - 项目类别:
Grant-in-Aid for Challenging Research (Exploratory)
Establishment of a strain of F8 gene-targeted pigs (hemophilia-A pigs) by xenografting of fetal testicular tissue from neonatally moribund cloned pigs
通过新生垂死克隆猪胎儿睾丸组织异种移植建立 F8 基因靶向猪(血友病 A 猪)品系
- 批准号:
26292171 - 财政年份:2014
- 资助金额:
$ 0.9万 - 项目类别:
Grant-in-Aid for Scientific Research (B)
Corrosion tests and assessments of nuclear reacter pressure vessel materials in solutions containing sea water and boric acid
核反应堆压力容器材料在海水和硼酸溶液中的腐蚀试验和评估
- 批准号:
24656433 - 财政年份:2012
- 资助金额:
$ 0.9万 - 项目类别:
Grant-in-Aid for Challenging Exploratory Research
Cryopreservation and improvement of developmental ability of porcine primordial oocytes
猪原始卵母细胞的冷冻保存及发育能力的提高
- 批准号:
21380175 - 财政年份:2009
- 资助金额:
$ 0.9万 - 项目类别:
Grant-in-Aid for Scientific Research (B)
Study on growth mechanism of thin films during electrodepostion at two-liquid interface by measuring interfacial tension
测量界面张力研究两液界面电沉积薄膜生长机理
- 批准号:
18360347 - 财政年份:2006
- 资助金额:
$ 0.9万 - 项目类别:
Grant-in-Aid for Scientific Research (B)
Preparations and specific properties of electroconductive films by electrodeposition at the interface between two liquid phases
两相界面电沉积导电薄膜的制备及其特性
- 批准号:
14350379 - 财政年份:2002
- 资助金额:
$ 0.9万 - 项目类别:
Grant-in-Aid for Scientific Research (B)
A Preliminary Examination on Cities and Gardens in Ancient East Asia
古代东亚城市与园林初探
- 批准号:
13410122 - 财政年份:2001
- 资助金额:
$ 0.9万 - 项目类别:
Grant-in-Aid for Scientific Research (B)
Electrochemical conditions for Separating purified metallic films by electrodeposition at the two-liquid-phase interface.
通过两液相界面电沉积分离纯化金属膜的电化学条件。
- 批准号:
11450268 - 财政年份:1999
- 资助金额:
$ 0.9万 - 项目类别:
Grant-in-Aid for Scientific Research (B)
Development of a novel method for preparing functional films by two-liquid-phase interface electrodeposition
一种两液相界面电沉积制备功能薄膜的新方法的开发
- 批准号:
08555167 - 财政年份:1996
- 资助金额:
$ 0.9万 - 项目类别:
Grant-in-Aid for Scientific Research (B)
Improved Electrodes for Zirconia Oxygen Sensor
氧化锆氧传感器的改进电极
- 批准号:
63550485 - 财政年份:1988
- 资助金额:
$ 0.9万 - 项目类别:
Grant-in-Aid for General Scientific Research (C)
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