Design of Multimetal Synergistic Systems with Linear Tetraphosphines and Their Use to Create Quantum Units
Design of Multimetal Synergistic Systems with Linear Tetraphosphines and Their Use to Create Quantum Units
批准号:
18350030
负责人:
TANASE Tomoaki
金额:
$10.23万
依托单位:
依托单位国家:
日本
项目类别:
Grant-in-Aid for Scientific Research (B)
财政年份:
2006
资助国家:
日本
项目状态:
已结题
起止时间:
2006 至 2008
中文摘要
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英文摘要
直鎖状に供与原子が配列した四座ホスフィンを合成し、それらを用いて種々の低原子価金属種との反応により1~2 nm の大きさを持つ様々な形状の遷移金属クラスターの合成を行い、詳細な構造や物性を明らかにするとともに、多金属中心の協同効果に基づく現象の発現や量子ユニット創製のための端緒を得るべく基礎的研究を行った。特に、白金やパラジウムでは直鎖状クラスター(Pt_6, Pd_8)を、また、金、銀、銅の貨幣金属を用いた場合には環状クラスター(Au_6,Au_6Cu_2, Au_4Cu_4, Au_4Ag_2Cu_2)を構築することができ、分子レベルでの構造や物性を明らかにするとともに、これらを構造単位としたナノ構造構築を目指し研究を行った。
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Dinuclear Rh(I)Complex with 2,7-Bis(diphenylphosphino)-1,8-nahthyridine: Synthesis, Structure, and Dynamic Property
2,7-双(二苯基膦)-1,8-二氮杂萘双核 Rh(I) 配合物:合成、结构和动态性质
DOI:
--
发表时间:
2007
期刊:
J. Organometallic Chemistry 692
影响因子:
--
作者:
[T. Tanase, H. Takenaka, E. Goto]
通讯作者:
E. Goto
Planar Tetranuclear and Dumbbell-shaped Octanuclear Pd Complexes with Bridging Silylene Ligands
具有桥连硅烯配体的平面四核和哑铃形八核 Pd 配合物
DOI:
--
发表时间:
2009
期刊:
Angew. Chem. Int. Ed 48
影响因子:
--
作者:
[山田哲行, 馬渡あかね, 田邊真, 小坂田耕太郎, 棚瀬知明]
通讯作者:
棚瀬知明
Transformation of Tetranuclear Copper(II) Complex Bridged by Sugar Phosphates into Nucleotide Containing Cu_4 Aggregations
糖磷酸酯桥联的四核铜(II)络合物转化为含Cu_4聚集体的核苷酸
DOI:
--
发表时间:
2006
期刊:
Eur. J, Inorg. Chem. (Elsevier)
影响因子:
--
作者:
[M.Kato, T.Tanase, M.Mikuriya]
通讯作者:
M.Mikuriya
Synthesis and Characterization of Multinuclear Transition Metal Complexes Containing {Cp*M} Fragments (M = Rh, Ir)Supported by Linearly Ordered Tetraphosphine Ligand
线性有序四膦配体支持的含 {Cp*M} 片段 (M = Rh, Ir) 的多核过渡金属配合物的合成与表征
DOI:
--
发表时间:
2008
期刊:
影响因子:
--
作者:
[Akiko Yoshii, Hiroko Nagata, Takayuki Nakajima, Tomoaki Tanase]
通讯作者:
Tomoaki Tanase
Dinuclear Rh(I)Complex with 2,7-Bis(diphenylphosphino)-1, 8-naphthyridi ne : Synthesis, Structure, and Dynamic Property
2,7-双(二苯基膦)-1, 8-萘啶双核 Rh(I) 配合物:合成、结构和动态性质
DOI:
--
发表时间:
2007
期刊:
J. Organomet. Chem. 692
影响因子:
--
作者:
[T. Tanase, H. Takenaka, and E. Goto]
通讯作者:
and E. Goto
共 10 条
New Materials Fabricated by Nano-Scale Dimensional Integration of Finely Constructed Multinuclear Metal Systems
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批准号:18H03914
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项目类别:Grant-in-Aid for Scientific Research (A)
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财政年份:2018
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依托单位:
Development of Carbon Nanotube Composite Materials Covered with Extended Metal Atom Chains
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依托单位:
Development of New Functional Materials by Nano-scale Molecular Design and Expansion of Multinuclear Metal Systems
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批准号:26288025
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Development of Artificial Photosystem with a Carbon Cycle by Designing Multinuclear Metal Complex Catalysts
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批准号:25620045
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财政年份:2013
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依托单位:
Molecular Chemical Strategy for Rare-Metal Materials Containing Platinum Which Contribute to Create Green Energy Systems
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批准号:21605008
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项目类别:Grant-in-Aid for Scientific Research (C)
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资助金额:$3.08万
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财政年份:2009
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负责人:TANASE Tomoaki
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依托单位:
Development of Structurally Constrained Metal Clusters Leading to Functional Nano-Molecular Devices
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批准号:13304053
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项目类别:Grant-in-Aid for Scientific Research (A)
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负责人:TANASE Tomoaki
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依托单位:
Development of Artificial Sugar-Transformation Systems by Biomimic Multimetallic Centers
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批准号:10440194
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项目类别:Grant-in-Aid for Scientific Research (B).
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资助金额:$6.14万
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财政年份:1998
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负责人:TANASE Tomoaki
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依托单位:
Nano-Scale Design of Metal-Metal Bonded Transition Metal Clusters and Their Assemblage with an Aim of Multifunctionarity
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批准号:09554038
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项目类别:Grant-in-Aid for Scientific Research (B)
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资助金额:$6.21万
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财政年份:1997
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负责人:TANASE Tomoaki
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依托单位:
Model Complexes for Non-Redox Active Metalloenzymes(Structural and Functional Model Complexes for Non-Redox Active Metalloenzymes Involving Dinuclear Metal Centers)
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批准号:09044103
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项目类别:Grant-in-Aid for international Scientific Research
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资助金额:$2.24万
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财政年份:1997
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负责人:TANASE Tomoaki
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依托单位:
Assembly of metal-metal bonds through small-size clusters
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批准号:08640725
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项目类别:Grant-in-Aid for Scientific Research (C)
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资助金额:$1.41万
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财政年份:1996
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负责人:TANASE Tomoaki
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依托单位:
海外基金