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Metal Catalyzed Reversible Conversion between Chemical Energy and Electrical One

Metal Catalyzed Reversible Conversion between Chemical Energy and Electrical One
金属催化化学能与电能之间的可逆转换
批准号:
20002005
负责人:
TANAKA Koji
金额:
$105.5万
依托单位国家:
日本
项目类别:
Grant-in-Aid for Specially Promoted Research
财政年份:
2008
资助国家:
日本
项目状态:
已结题
起止时间:
2008 至 2011

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中文摘要
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英文摘要
Irradiation of visible light to newly prepared Ru^<II> complexes enabled C-H bond formation using water molecules as the hydrogen source. The process for O-O bond formation through a coupling reaction of two water molecules was detected for the first time by the Resonance Raman spectra of a dinuclear Ru complex that has an ability to catalyze four electron oxidation of water. An Ru^<III>-oxyl radical complex showed novel functionalities in the oxidation of methanol as hydrogen atom acceptor and one electron receiver, respectively.
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Photo-and Electrochemical Redox Behavior of Ru(II) Complexes having Cyclometalated 3-Phenylbenzo[b][1, 6]-naphthyridine(phbn)
环金属化 3-苯基苯并[b][1, 6]-萘啶 (phbn) 的 Ru(II) 配合物的光和电化学氧化还原行为
DOI: --
发表时间: 2012
期刊: Inorg. Chem
影响因子: --
作者: [Ligand, S. K. Padhi, K. Tanaka]
通讯作者: K. Tanaka
DOI: --
发表时间: 2011
期刊: Dalton Trans
影响因子: --
作者: [T. Teratani, T. Koizumi, T. Yamamoto, K. Tanaka, T. Kanbara]
通讯作者: T. Kanbara
Proton Induced Dynamic Equilibrium between Cyclometalated Ru(II) and rNHC remote N-Heterocyclic Carbene) Ru(IV) Tautomers with an NAD+/NADH Function
具有 NAD /NADH 功能的环金属化 Ru(II) 和 rNHC 远程 N-杂环卡宾 Ru(IV) 互变异构体之间的质子诱导动态平衡
DOI: --
发表时间: 2011
期刊:
影响因子: --
作者: [Sumanta Kumar Padhi, Koji Tanaka]
通讯作者: Koji Tanaka
Electronic structures of dinuclear Ru-dioxolene complexes and reactivity toward four-electron oxidation of water
双核Ru-二氧杂环戊烯配合物的电子结构及其对水四电子氧化的反应性
DOI: --
发表时间: 2010
期刊:
影响因子: --
作者: [Kawasaki N., Sakamoto N. and Yurimoto H., K. Tanaka]
通讯作者: K. Tanaka
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    The development of educational program based on a decision-making model for information ethical behavior
    Research on the genealogy of annotative research of early modern Japanese classical literature
    Development of therapeutic nursing practice that contributes to improving the resilience of older adults with depression
    • 批准号:
      26861972
    • 项目类别:
      Grant-in-Aid for Young Scientists (B)
    • 资助金额:
      $2.41万
    • 财政年份:
      2014
    • 负责人:
      TANAKA Koji
    • 依托单位:
    Development of the evaluation standard of behavioral and psychological symptoms of dementia
    • 批准号:
      24500590
    • 项目类别:
      Grant-in-Aid for Scientific Research (C)
    • 资助金额:
      $3.0万
    • 财政年份:
      2012
    • 负责人:
      TANAKA Koji
    • 依托单位:
    海外基金