Development of chemical fixation of ubiquitous molecules with bifunctional molecular catalysts

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On the basis of our accumulated knowledge in the bifunctional catalysis, we tried 1) to design new mono- and multi-nuclear transition metal-based complexes bearing cooperating ligands, and 2) to demonstrate perfect chemical reactions by extension of the scope of the applicability of the bifunctional catalysis, and finally 3) to explore the chemical fixation of the ubiquitous molecules into useful compounds and materials by development of the practical bifunctional molecular catalysts. The emergence of powerful bifunctional molecular catalysts provided efficient, sustainable and green production processes in the field of organic synthesis. In addition, the bifunctional catalyst promoted powerful chemical fixation technology of ubiquitous molecules including H2O, H2, O2, N2, and CO2 available in huge amounts can help to replace the fossil resources.