Syntheses of novel lithium-ion conductors by using inorganic-organic hybrid layered crystals

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Inorganic-organic hybrid crystals containing polyoxometalate inorganic cluster anion and cationic surfactant were successfully synthesized by a simple cation-exchange solution process. These hybrid crystals, which are rare series of materials, consisted of alternate stacking manner of polyoxometalate inorganic layers and surfactant organic layers. In addition, polyoxometalate-surfactant hybrid crystals containing metal ions or protons were obtained. These hybrid crystals exhibited anhydrous conductivity at intermediate temperature range over 373 K, and are promising candidates for ion-conductive solid electrolytes.