Development and Application of Organocatalyst for Activation of Gas Molecule

尽管使用均相过渡金属催化加氢是关键技术之一，但过渡金属配合物价格昂贵，通常需要去除反应产物中的金属杂质。近年来，利用三（全氟苯基）硼烷实现了无金属氢化。为了发展反应体系，我们合成了一类新的三芳基硼烷。结果表明，三芳基硼烷在邻基参与下是稳定的。

Even though the use of homogeneous transition metal catalytic hydrogenation is one of the key technologies, transition metal complexes are expensive, and the removal of metal impurities from the reaction product is generally required. Recently, metal-free hydrogenation has been accomplished using tris(perfluorophenyl)borane. In order to develop the reaction system, we synthesized new class of triaryl boranes. As the result, it has been found that triaryl boranes are stabilized by neighboring group participation.