CO2 Post-Combustion Capture Using Amine Impregnated Synthetic Zeolites

使用胺浸渍的合成沸石捕获燃烧后二氧化碳

• 批准号: EP/L020777/1
• 负责人: Colin Snape
• 金额: $ 24.48万
• 依托单位: University of Nottingham
• 依托单位国家: 英国
• 项目类别: Research Grant
• 财政年份: 2014
• 资助国家: 英国
• 起止时间: 2014 至 无数据
• 项目状态: 已结题
• 来源: https://gtr.ukri.org/projects?ref=EP%2FL020777%2F1
• 关键词: CO2; Post; Combustion; Capture; Using

This proposal addresses Topic 4 in the Call: New innovative CO2 capture technologies. The proposed research will address using synthetic zeolites obtained from fly ash to support impregnated and immobilised amines to facilitate CO2 post-combustion capture (PCC) in both coal and natural gas power plants. One of the barriers to the widespread implementation of CO2 in power plants is the energy cost associated with solvent regeneration in the most mature PCC technology, amine scrubbing, which will be even greater for gas-fired power plants because of the lower CO2 concentration, higher O2 concentration and higher flue gas flow rate compared to similar sized coal-fired power plant. Hence, alternative or second generation PCC technologies need to be developed that have the potential to lower this energy penalty and also have lower capital and operating costs. Solid adsorbent looping technology (SALT) is a novel, potentially low-cost that can overcome the main drawbacks of amine absorption. The technology relies upon adsorbents that can achieve high CO2 uptakes at relatively low temperatures with short residence times. Amines either impregnated or immobilsed on mesoporous materials, particularly aluminosilicates, have been found to be particularly effective.In the proposed research, zeolites produced from fly ash will be optimised for PCC as a route that will considerably reduce the preparation costs for basic adsorbents. The project will combine the respective strengths of MEERI/Lublin and the University of Nottingham in zeolite synthesis and developing basic adsorbents for PCC. The zeolites will be produced at Lublin on a scale of several kilograms to facilitate testing in a fluidised bed with real (gas-fired) flue gases at Nottingham. The production cost is estimated to be ca. 1 euro/kg of zeolite, which is considerably lower than using silicas and zeolites produced from traditional sources. The successful outcome of the proposed research will contribute to making SALT a more cost-effective process for PCC.

该提案涉及呼吁中的主题4：新型创新CO2捕集技术。拟议的研究将解决使用从粉煤灰中获得的合成沸石来支持浸渍和固定的胺，以促进煤炭和天然气发电厂的CO2燃烧后捕获（PCC）。在发电厂中广泛实施CO2的障碍之一是与最成熟的PCC技术中的溶剂再生（胺洗涤）相关的能量成本，与类似规模的燃煤发电厂相比，由于较低的CO2浓度、较高的O2浓度和较高的烟道气流速，这对于燃气发电厂将更高。因此，需要开发替代或第二代PCC技术，其具有降低这种能量损失的潜力，并且还具有较低的资本和运营成本。固体吸附剂循环技术（SALT）是一种新型的，潜在的低成本，可以克服胺吸收的主要缺点。该技术依赖于可以在相对较低的温度下以较短的停留时间实现高CO2吸收的吸附剂。胺无论是浸渍或固定在介孔材料，特别是铝硅酸盐，已被发现是特别有效的。在拟议的研究中，从粉煤灰生产的沸石将优化PCC作为一种路线，这将大大降低碱性吸附剂的制备成本。该项目将联合收割机结合MEERI/Lublin和诺丁汉大学在沸石合成和开发PCC基础吸附剂方面的各自优势。沸石将在卢布林以几公斤的规模生产，以便于在诺丁汉用真实的（燃气）烟道气在流化床中进行测试。生产成本估计为1000万美元。1欧元/千克的沸石，这比使用由传统来源生产的二氧化硅和沸石低得多。拟议研究的成功结果将有助于使SALT成为PCC的更具成本效益的工艺。

项目成果

Synthesis and characterization of zeolites prepared from industrial fly ash.

用工业粉煤灰制备的沸石的合成和表征。

• DOI: 10.1007/s10661-014-3815-5
• 发表时间: 2014-09
• 期刊: ENVIRONMENTAL MONITORING AND ASSESSMENT
• 影响因子: 3
• 作者: Franus, Wojciech;Wdowin, Magdalena;Franus, Magorzata
• 通讯作者: Franus, Magorzata

Experimental study of mercury removal from exhaust gases

• DOI: 10.1016/j.fuel.2014.03.041
• 发表时间: 2014-07
• 期刊: Fuel
• 影响因子: 7.4
• 作者: M. Wdowin;Małgorzata M. Wiatros-Motyka;R. Panek;Lee Stevens;W. Franus;C. Snape

REMOVAL OF ENVIRONMENTAL POLLUTIONS USING ZEOLITES FROM FLY ASH: A REVIEW

• 发表时间: 2015
• 作者: M. Wdowin;L. Bandura;W. Franus

The conversion technology of fly ash into zeolites

• DOI: 10.1007/s10098-014-0719-6
• 发表时间: 2014-08-01
• 期刊: CLEAN TECHNOLOGIES AND ENVIRONMENTAL POLICY
• 影响因子: 4.3
• 作者: Wdowin, Magdalena;Franus, Malgorzata;Franus, Wojciech
• 通讯作者: Franus, Wojciech

Fly ash-derived MCM-41 as a low-cost silica support for polyethyleneimine in post-combustion CO2 capture

• DOI: 10.1016/j.jcou.2017.09.015
• 发表时间: 2017-12-01
• 期刊: JOURNAL OF CO2 UTILIZATION
• 影响因子: 7.7
• 作者: Panek, R.;Wdowin, M.;Snape, C. E.
• 通讯作者: Snape, C. E.