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MULTIFREQUENCY EPR OF RHENIUM VI IN KEGGIN TYPE POLYANIONS

MULTIFREQUENCY EPR OF RHENIUM VI IN KEGGIN TYPE POLYANIONS
Keggin型聚阴离子中铼VI的多频EPR
批准号:
6120712
负责人:
MARK R NILGES
金额:
$0.27万
依托单位国家:
美国
项目类别:
财政年份:
1998
资助国家:
美国
项目状态:
已结题
起止时间:
1998-04-15 至 1999-11-30

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中文摘要
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英文摘要
Multifrequency EPR, X-band, Q-band, W-band, have been recorded to enable the interpretation of the unusual and very remarkable EPR spectra of this Rhenium compound. The EPR spectra of this system spans nearly one Tesla, and the number of observable transitions depends heavily on frequency. Simulation of the spectra are carried out at several frequencies using advanced simulation routines that take into account high-order effects that are expected for systems with large hyperfine splittings.
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