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PULSED EPR STUDIES OF BIOLOGICAL MANGANESE CLUSTERS

PULSED EPR STUDIES OF BIOLOGICAL MANGANESE CLUSTERS
生物锰簇的脉冲 EPR 研究
批准号:
6309057
负责人:
R David Britt
金额:
$2.74万
依托单位国家:
美国
项目类别:
财政年份:
2000
资助国家:
美国
项目状态:
已结题
起止时间:
2000-02-01 至 2002-01-14

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中文摘要
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英文摘要
The SIR provided [4'-44% 17 O]Tyrosine; 1.3g We plan to do pulsed ENDOR studies on 17) labelled tyrosine radicals as part of our investigations into how a Photosystem H tyrosine radical together with the Mn cluster of PSH oxidize water. The first efforts will be on UV-generated tyrosine radicals. We plan to use pulsed ENDOR to dtudy motion of such radicals by examining the ENDOR lineshapes as a function of temperature. Similar studies will then be performed on the 170 tyrosine incorporated into PSII
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