Catalytic C-element bond cleavage and functional group transfer by metal NHC complexes

金属 NHC 配合物催化 C 元素键断裂和官能团转移

• 批准号: 1940959
• 金额: --
• 依托单位: University of Edinburgh
• 依托单位国家: 英国
• 项目类别: Studentship
• 财政年份: 2017
• 资助国家: 英国
• 起止时间: 2017 至 无数据
• 项目状态: 已结题
• 来源: https://gtr.ukri.org/projects?ref=studentship-1940959
• 关键词: Catalytic; element; bond; cleavage; functional

Aim is to develop stoichiometric and catalytic activation, cleavage, and functionalisation of small organic molecules with a wide range of metal complexes and enantioselective organocatalysis.4 Bifunctional NHCs will be used to catalytically activate small polar organic molecules to cleave polar C-E bonds, and to facilitate catalytic enantioselective sulfonation and phosphorylation to prepare selectively O-S and O-P bonds.

目的是开发化学计量和催化活化，裂解，和功能化的小有机分子与广泛的金属配合物和对映选择性有机催化。4双官能NHC将用于催化活化小极性有机分子，以裂解极性C-E键，并促进催化对映选择性磺化和磷酸化，以选择性地制备O-S和O-P键。