Atomic and electronic structure of perovskite/oxides interfaces

钙钛矿/氧化物界面的原子和电子结构

• 批准号: 2107057
• 金额: --
• 依托单位: University of York
• 依托单位国家: 英国
• 项目类别: Studentship
• 财政年份: 2018
• 资助国家: 英国
• 起止时间: 2018 至 无数据
• 项目状态: 已结题
• 来源: https://gtr.ukri.org/projects?ref=studentship-2107057
• 关键词: Atomic; electronic; structure; perovskite; oxides

Perovskite solar cells (PSCs) have potentials to revolutionise the field of solar cells. Their efficiency in the last decades has increased by order of magnitude, which is unprecedented in the field of the solar cells. In addition, they are cheap to be made and easy to manufacture. Hence, the tremendous interest in perovskite solar cells as next generation of efficient and cost effective solar cells. Further efficiency enhancement, improving their stability as well as making them environmentally friendly requires fundamental understanding of the interfaces between the oxide electrode (e.g. n type-TiO2 and p type - NiO) and perovskite layer. This project aims to address the role of the interfaces regarding charge trapping and charge recombination processes which ultimately reduces the solar cell efficiency.The main objectives is to understand the structure and chemistry of oxide electrodes and the interface they create in contact with the perovskite absorber layer. In addition the role of dopants and their effect on the internal oxide boundaries and oxide-perovskite interfaces properties will be determined. This will be done by employing state of the art atomic resolution electron microscopy imaging and spectroscopy coupled with quantum mechanical calculations. Achieving of this goal will enable developing new doping strategy as well as developing growth strategy for creating more efficient and stable perovskite solar cells. This project will be conducted jointly with GreatCell Solar Ltd. The full solar cells structures will be fabricate and optically characterised by GreatCell Sollar, the PhD student will be involved in the processes, while at York he will perform structural characterisation and modelling on atomic level and will correlate the functional to structural properties of the fabricated solar cells. In addition, model interfaces of oxide-perovskite layers will be grown and fully characterised at York.

永久性太阳能电池（PSCs）具有革新太阳能电池领域的潜力。在过去的几十年中，它们的效率以数量级增加，这在太阳能电池领域是前所未有的。此外，它们的制造成本低，易于制造。因此，钙钛矿太阳能电池作为下一代高效且具有成本效益的太阳能电池受到极大关注。进一步提高效率、改善其稳定性以及使其环境友好需要对氧化物电极（例如n型-TiO 2和p型- NiO）和钙钛矿层之间的界面的基本理解。该项目旨在解决界面在电荷捕获和电荷复合过程中的作用，这些过程最终会降低太阳能电池的效率。主要目标是了解氧化物电极的结构和化学性质以及它们与钙钛矿吸收层接触时产生的界面。此外，还将确定掺杂剂的作用及其对内部氧化物边界和氧化物-钙钛矿界面性质的影响。这将通过采用最先进的原子分辨率电子显微镜成像和光谱与量子力学计算相结合来完成。实现这一目标将有助于开发新的掺杂策略，以及开发更高效、更稳定的钙钛矿太阳能电池的生长策略。该项目将与GreatCell Solar Ltd.联合进行。完整的太阳能电池结构将由GreatCell Sollar制造并进行光学表征，博士生将参与该过程，而在约克，他将在原子水平上进行结构表征和建模，并将制造的太阳能电池的功能与结构特性相关联。此外，氧化物-钙钛矿层的模型界面将在约克生长并充分表征。