Non-Covalent Assembly of Functional Nanostructures
功能纳米结构的非共价组装
基本信息
- 批准号:EP/C545273/1
- 负责人:
- 金额:$ 108.61万
- 依托单位:
- 依托单位国家:英国
- 项目类别:Fellowship
- 财政年份:2006
- 资助国家:英国
- 起止时间:2006 至 无数据
- 项目状态:已结题
- 来源:
- 关键词:
项目摘要
This is an application for a European Young Investigator Award for Andrei Khlobystov (AK). Recently the importance of nanostructures such as quantum dots and endohedral fullerenes for various applications (such as high speed electronics, stable memory elements) has been recognised. Much effort has been placed on learning about properties of isolated nanostructures, but the development and understanding of ordered arrays of these materials has just begun to be explored. The central aim of this application is to develop a technology for assembling functional networks of magnetically and/or optically active centres whose quantum states can interact with each other over distances exceeding molecular dimensions. I propose to connect active nano-objects via conducting nanowires through applying coordination and supramolecular chemistry at the nanoscale. There are three major challenges in fabrication of such nanostructures: (1) chemical functionalisation of nanoscopic building blocks for networks, (2) positional and orientational control of nano-objects on the surface, and (3) fine tuning of electronic properties of nanowires mediating interactions in networks. These challenges will be addressed by utilising the versatile coordination and supramolecular chemistry, photo- or electrochemistry on the nanoscale. The new materials are expected to exhibit a range of unusual and testable magnetic, optical and catalytic properties. The metal-directed supramolecular assembly of nanoparticles and nanowires will be used for controlling their alignment. The highly directional coordination interactions between metal functionalised nanoscopic building blocks will allow construction of polymeric architectures with desired topology and geometry. This novel interdisciplinary approach will advance the understanding of fundamental aspects of self-assembly on the nanoscale, and will produce new materials that are commercially useful for applications, such as memory elements, quantum computing, molecular sensors, or optoelectronic devices.
这是Andrei Khlobystov (AK)申请欧洲青年研究者奖的申请。最近,人们认识到量子点和内嵌富勒烯等纳米结构在各种应用(如高速电子、稳定存储元件)中的重要性。人们在学习孤立纳米结构的性质上已经付出了很多努力,但对这些材料的有序阵列的开发和理解才刚刚开始探索。本应用程序的中心目标是开发一种技术,用于组装磁性和/或光学活性中心的功能网络,其量子态可以在超过分子尺寸的距离上相互作用。我建议在纳米尺度上运用配位和超分子化学,通过导电纳米线连接有活性的纳米物体。制造这种纳米结构面临三个主要挑战:(1)纳米级网络构建块的化学功能化,(2)表面纳米物体的位置和方向控制,以及(3)介导网络中相互作用的纳米线的电子特性的微调。这些挑战将通过在纳米尺度上利用多功能配位和超分子化学、光化学或电化学来解决。新材料有望展现出一系列不同寻常的、可测试的磁性、光学和催化性能。纳米粒子和纳米线的金属定向超分子组装将用于控制它们的排列。金属功能化纳米级构建块之间的高度定向配位相互作用将允许构建具有所需拓扑和几何形状的聚合物结构。这种新颖的跨学科方法将促进对纳米尺度上自组装基本方面的理解,并将产生对存储元件、量子计算、分子传感器或光电器件等商业应用有用的新材料。
项目成果
期刊论文数量(10)
专著数量(0)
科研奖励数量(0)
会议论文数量(0)
专利数量(0)
Electron microscopy of carbon nanotubes
- DOI:10.1134/1.1387123
- 发表时间:2001-07
- 期刊:
- 影响因子:0.7
- 作者:N. Kiselev;D. Zakharov
- 通讯作者:N. Kiselev;D. Zakharov
Functionalised Fullerenes in Carbon Nanotubes: Controlled Assembly of Molecular Chains
碳纳米管中的功能化富勒烯:分子链的受控组装
- DOI:
- 发表时间:
- 期刊:
- 影响因子:0
- 作者:Andrei Khlobystov (Author)
- 通讯作者:Andrei Khlobystov (Author)
Chemistry in Carbon Nanotubes
碳纳米管化学
- DOI:
- 发表时间:
- 期刊:
- 影响因子:0
- 作者:Andrei Khlobystov (Author)
- 通讯作者:Andrei Khlobystov (Author)
Interactions of Carbon Nanotubes with Molecules and Colloidal Nanoparticles
碳纳米管与分子和胶体纳米颗粒的相互作用
- DOI:
- 发表时间:
- 期刊:
- 影响因子:0
- 作者:Andrei Khlobystov (Author)
- 通讯作者:Andrei Khlobystov (Author)
Carbon Nanotubes and Graphene as Containers for Molecules and Nanoparticles
碳纳米管和石墨烯作为分子和纳米颗粒的容器
- DOI:
- 发表时间:
- 期刊:
- 影响因子:0
- 作者:Andrei Khlobystov (Author)
- 通讯作者:Andrei Khlobystov (Author)
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Andrei Khlobystov其他文献
Andrei Khlobystov的其他文献
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{{ truncateString('Andrei Khlobystov', 18)}}的其他基金
Metal Atoms on Surfaces & Interfaces (MASI) for Sustainable Future
表面上的金属原子
- 批准号:
EP/V000055/1 - 财政年份:2021
- 资助金额:
$ 108.61万 - 项目类别:
Research Grant
High resolution, cryogenic analytical and transfer scanning electron microscope (HR-CAT-SEM)
高分辨率、低温分析和转移扫描电子显微镜 (HR-CAT-SEM)
- 批准号:
EP/S021434/1 - 财政年份:2019
- 资助金额:
$ 108.61万 - 项目类别:
Research Grant
NanoPrime: Maximising Equipment and Expertise Sharing in Nanoscience
NanoPrime:最大限度地共享纳米科学的设备和专业知识
- 批准号:
EP/R025282/1 - 财政年份:2018
- 资助金额:
$ 108.61万 - 项目类别:
Research Grant
Triggering, Controlling and Imaging Chemical Reactions at the Single-Molecule Level by Electron Beam
通过电子束触发、控制和成像单分子水平的化学反应
- 批准号:
EP/R024790/1 - 财政年份:2018
- 资助金额:
$ 108.61万 - 项目类别:
Fellowship
Elucidating the potential interaction of manufactured nanoparticles with polycyclic aromatic hydrocarbons: an integrated toxicogenomics approach
阐明人造纳米粒子与多环芳烃的潜在相互作用:综合毒物基因组学方法
- 批准号:
NE/L006138/1 - 财政年份:2014
- 资助金额:
$ 108.61万 - 项目类别:
Research Grant
Multi-Functional Nanoscale Platforms: Bridging the Gap between Molecular and Macroscopic Worlds
多功能纳米平台:弥合分子世界和宏观世界之间的差距
- 批准号:
EP/L014696/1 - 财政年份:2013
- 资助金额:
$ 108.61万 - 项目类别:
Research Grant
IDEAS Factory - Chemical Craftwork: Directed Assembly of Functional Patterns (Brianchell)
IDEAS Factory - 化学工艺:功能图案的定向组装 (Brianchell)
- 批准号:
EP/D023777/1 - 财政年份:2006
- 资助金额:
$ 108.61万 - 项目类别:
Research Grant
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