Bifunctional metal complexes with triaylboron groups: photophysical properties, reactivity, and chemical sensing

具有三芳基硼基团的双功能金属配合物：光物理性质、反应性和化学传感

• 批准号: 193993-2008
• 负责人: Wang, Suning
• 金额: $ 7.29万
• 依托单位: Queen's University
• 依托单位国家: 加拿大
• 项目类别: Discovery Grants Program - Individual
• 财政年份: 2012
• 资助国家: 加拿大
• 起止时间: 2012-01-01 至 2013-12-31
• 项目状态: 已结题
• 来源: https://www.nserc-crsng.gc.ca/ase-oro/Details-Detailles_eng.asp?id=513996
• 关键词: Bifunctional; metal; complexes; triaylboron; groups

Triarylboron compounds are an important class of materials for optoelectronic devices and anion sensing applications due to their Lewis acidity/electron accepting ability and their fluorescence. Transition metal complexes, in contrast, are well known for their catalytic reactivity, their colors, and their ability to greatly enhance phosphorescence, a highly desired property for organic light emitting diodes (OLEDs) and oxygen sensors. This proposal concerns the development of synthetic methods for hybrid compounds that contain both transition metal ions and triarylboron groups and the investigation of photophysical properties and potential applications of the new compounds.

三芳基硼化合物由于其刘易斯酸性/电子接受能力和它们的荧光性而成为用于光电器件和阴离子传感应用的一类重要材料。相比之下，过渡金属络合物因其催化反应性、颜色和极大增强磷光的能力而众所周知，磷光是有机发光二极管（OLED）和氧传感器高度期望的性质。本论文的主要工作是发展含过渡金属离子和三芳基硼基团的杂化化合物的合成方法，并对这些新化合物的物理性质和潜在应用进行研究。