Development of Stimuli-responsive Polymer Hybrid Materials

刺激响应聚合物杂化材料的开发

• 批准号: RGPIN-2016-04101
• 负责人: Zhao, Yue
• 金额: $ 5.46万
• 依托单位: Université de Sherbrooke
• 依托单位国家: 加拿大
• 项目类别: Discovery Grants Program - Individual
• 财政年份: 2017
• 资助国家: 加拿大
• 起止时间: 2017-01-01 至 2018-12-31
• 项目状态: 已结题
• 来源: https://www.nserc-crsng.gc.ca/ase-oro/Details-Detailles_eng.asp?id=632252
• 关键词: Development; Stimuli; responsive; Polymer; Hybrid

Our research program aims to discover smart materials comprising an organic polymer and an inorganic nanoparticle, which can accomplish a specific function by responding to stimuli as a result of concerted action of the two constituents. On the one hand, using the photothermal effect generated by gold nanoparticles (AuNPs) or nanorods (AuNRs), we develop the next-generation polymers that not only can undergo light-controlled reversible deformation and motion but also can be reprocessed or reshaped. On the other hand, we propose to develop a unique type of nanoreactors and nanovectors for stimuli-switchable catalysis and stimuli-controlled cargo release, respectively. These nanosystems are built up with either an AuNP or AuNR or upconverting nanoparticle (UCNP) inside a hollow polymer shell. Through rational design, in aqueous solution the polymer shell can switch between a swollen (open) and shrunk (closed) state upon a small change in temperature or pH or upon exposure to light, which activates or shuts down the catalytic activity of AuNPs of the nanoreactor, or the release of cargo from the nanovector. These novel functional materials could offer unprecedented performance and find many possible applications.

我们的研究计划旨在发现由有机聚合物和无机纳米颗粒组成的智能材料，这种材料可以通过对这两种成分协同作用的刺激做出反应来完成特定的功能。一方面，利用金纳米颗粒(AuNPs)或纳米棒(AuNRs)产生的光热效应，我们开发了新一代聚合物，不仅可以进行光控可逆变形和运动，还可以进行二次加工或重塑。另一方面，我们建议开发一种独特的纳米反应器和纳米矢量，分别用于刺激可切换催化和刺激控制货物释放。这些纳米系统是由AuNP或AuNR或上转换纳米粒子(UCNP)在中空聚合物外壳内构建而成的。通过合理的设计，在水溶液中，聚合物壳层可以在温度或pH的微小变化或暴露在光下时在膨胀(打开)和收缩(关闭)状态之间切换，从而激活或关闭纳米反应器的AuNPs的催化活性，或者从纳米矢量器释放货物。这些新颖的功能材料可以提供前所未有的性能，并找到许多可能的应用。