Synthesis and Chemistry of Polycyclic Systems

9313413伊顿有机动力学计划的这一资助支持了 芝加哥大学的伊顿教授继续说， 的合成、反应性和性质的研究 多环碳氢化合物基于铜框架。 寻求脱氢古巴烷的表征和利用： 立方烯、1，3-脱氢立方烷、1，4-立方烷二基和更高级的二基。 由1，4-立方烷二基合成定义的刚性棒材料 寻求几何形状和长度。低聚和聚立方烷也将 将重点放在多环辛四烯的合成上 和聚乙炔，并旨在产生材料， 导电性能和高的碳/氢比。 在这个项目中，伊顿教授继续探索 形成的一类特殊的多环碳氢化合物化学 古巴人。本研究的重点是 表征和利用各种不饱和 脱氢立方烷体系。这项研究将探索可溶性的 具有确定性能和导电性的刚性杆材料 烃作为聚和低聚立方烷的应用。 ***

9313413 Eaton This grant from the Organic Dynamics Program supports the work of Professor Eaton at the University of Chicago for continued studies on the synthesis, reactivities, and properties of polycyclic hydrocarbons based on the cubyl frame. Characterization and utilization is sought of the dehydrocubanes: cubene, 1,3-dehydrocubane, 1,4-cubane diyl, and the higher diyls. Synthesis from 1,4-cubane diyl of rigid-rod materials of defined geometry and lengths is sought. Oligo- and polycubanes will also be pursued with focus on the synthesis of polycyclooctatetraenes and polyacetylenes and is aimed toward generating materials with conducting properties and with high carbon/hydrogen ratios. %%% In this project Professor Eaton continues to explore the chemistry of the special class of polycyclic hydrocarbons formed from cubanes. The emphasis of this research is on the characterization and utilization of the various unsaturated dehydrocubane systems. The research will venture out to soluble rigid-rod materials of defined properties and conducting hydrocarbons as applications from poly- and oligocubanes. ***