Collaborative Research: Sodiation Driven Multiscale Chemical-Structural Interactions in Alloy Electrodes

迫切需要大幅增加可再生能源在电网中的整合。这些可再生资源固有的间歇性和分散性决定了具有成本效益的大规模能源储存的发展。这种存储能力提供了额外的好处，即为电网提供弹性，这是减轻自然灾害和其他灾难性事件的影响所必需的。基于地球的电化学储能技术的需求越来越大，材料丰富且经济实惠。钠离子电池和锡(锡)基合金负极材料是这一需要大容量储能的应用的很有前途的技术。通过这一基础研究项目，在锡基合金中钠储存引起的化学和结构变化与由此产生的钠离子电池性能之间建立了更强的联系。该研究项目有助于在多学科研究环境中对研究生和本科生进行教育和培训。综合教育和推广计划将为研究生、本科生和高中生创造参与这项研究的机会，并强调增加来自代表性不足群体的学生的参与。研究成果将通过讲座和实验室课程纳入本科生和研究生的课程。从全面的实验、表征和模拟工作中产生的开放源码数据库将导致能量存储科学的进步。通过促进钠离子电池的未来发展，该项目将有助于满足社会对具有成本效益的电网储能的需求。这项研究的主要目标是开发一个全面的知识库，并了解高容量锡(锡)基钠离子电池合金电极的化学和结构转变。这项工作是基于这样一个假设，即盐化引起的介观形态和化学成分的变化对这种合金电极的不可逆容量有很大贡献。一项包括电化学测试、电极晶体结构的X射线衍射表征、以及手术中的X射线层析成像在内的实验计划将与钠离子电池电极微结构的中尺度计算研究相结合。这种综合研究方法将通过实现以下研究目标来验证上述假设：(1)将锡基合金电极晶体结构的变化与电化学性能相关联；(2)将多尺度合金电极形态与结构和化学变化相关联；(3)阐明电极微结构对传输-电化学相互作用和性能的影响。这项研究将对钠离子电池的微观结构、化学和性能之间的相互作用提供深入的见解。实验和计算相结合的方法将提供关于由于盐化而导致的合金电极的化学和结构演变的前所未有的细节。所获得的见解将促进未来钠离子电池电极的工程设计，并将产生适用于与其他电池化学相关的一系列电极材料的方法。拟议的X射线成像和中尺度建模工作将产生一组记录在案的3D微结构数据，这些数据将通过开放源代码平台传播，并将支持未来的研究和开发。该奖项反映了NSF的法定使命，并通过使用基金会的智力优势和更广泛的影响审查标准进行评估，被认为值得支持。

There is a critical need to dramatically increase the integration of renewable energy in the electric grid. The inherently intermittent and diffuse nature of these renewable resources predicates the development of cost-effective, large-scale energy storage. Such storage capabilities offer the added benefit of contributing resilience to the electric grid, which is needed to mitigate the effects of natural disasters and other catastrophic events. Electrochemical energy storage technologies based on earth abundant and cost-effective materials are increasingly needed. The sodium ion battery and tin (Sn) based alloy anode materials are promising technologies for this application that needs high-capacity energy storage. Through this fundamental research project, stronger connection is made between the chemical and structural changes due to sodium storage in Sn-based alloys and the resulting performance of the sodium ion battery. The research project contributes to the education and training of both graduate and undergraduate students within a multidisciplinary research environment. The integrated education and outreach plan will create opportunities for graduate, undergraduate, and high school students to be involved in this research and places a strong emphasis on increasing the participation of students from underrepresented groups. Research findings will be integrated into the curriculum at the undergraduate and graduate level through lectures and laboratory classes. A library of open-source data generated from the comprehensive experiment, characterization, and simulation efforts will lead to the advancement of energy storage science. By facilitating the future development of sodium ion batteries, the project will help contribute to the societal need for cost-effective grid energy storage. The principal objective of this research is to develop a comprehensive knowledge base and understanding of the chemical and structural transformations in high-capacity tin (Sn) based alloy electrodes for sodium ion batteries. This work is predicated on the hypothesis that changes in mesoscale morphology and chemical composition caused by sodiation contribute significantly to the irreversible capacity of such alloy electrodes. An experimental program including electrochemical testing, X-ray diffraction characterization of electrode crystal structure, and in operando X-ray tomography will be coupled with mesoscale computational studies of sodium ion battery electrode microstructures. This comprehensive research approach will test the above hypothesis by achieving these research objectives: (1) correlate changes in Sn-based alloy electrode crystal structure with electrochemical performance; (2) correlate multiscale alloy electrode morphology with structural and chemical changes; and (3) clarify the influence of electrode microstructure on the transport-electrochemistry interaction and performance. The research will provide insight into the interactions between microstructure, chemistry, and performance in sodium ion batteries. The combined experimental and computational approach will provide unprecedented details on the chemical and structural evolution of alloy electrodes due to sodiation. The insights gained will facilitate engineering of future sodium ion battery electrodes and will yield methods applicable to an array of electrode materials relevant to other battery chemistries. The proposed X-ray imaging and mesoscale modeling efforts will yield a documented set of 3D microstructural data, which will be disseminated through an open-source platform and will support future research and development.This award reflects NSF's statutory mission and has been deemed worthy of support through evaluation using the Foundation's intellectual merit and broader impacts review criteria.